(1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

Base Information

Chemical Name:(1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside
CAS No.:650635-12-4
Molecular Formula:C₁₉H₃₄O₇
Molecular Weight:374.475
Hs Code.:

Synonyms:(1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

Suppliers and Price of (1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

There total 7 articles about (1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 649723-27-3
2,2-Dimethyl-propionic acid (S)-1-methyl-3-[(R)-2,6,6-trimethyl-4-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-cyclohex-1-enyl]-propyl ester

: 650635-12-4
(1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

Guidance literature:: With lithium hydroxide; In methanol; for 20h; Heating;
DOI:10.1248/cpb.51.878

Reference yield:

: 322474-89-5
Acetic acid (R)-4-((S)-3-hydroxy-but-1-ynyl)-3,5,5-trimethyl-cyclohex-3-enyl ester

: 650635-12-4
(1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 78 percent / H₂ / Pd/C / ethanol / 3 h / 20 °C

2: pyridine / 15 h / 20 °C

3: 727 mg / NaOMe / methanol / 2 h / 20 °C

4: 48 percent / AgOTf; N,N-tetramethylurea; 4A molecular sieves / CH₂Cl₂ / 2.5 h / 0 - 20 °C

5: 95 percent / LiOH*H₂O / methanol / 20 h / 20 °C

6: 74 percent / LiOH*H₂O / methanol / 20 h / Heating

With pyridine; lithium hydroxide; 4 A molecular sieve; hydrogen; sodium methylate; silver trifluoromethanesulfonate; tetramethylurea; palladium on activated charcoal; In methanol; ethanol; dichloromethane;
DOI:10.1248/cpb.51.878

Reference yield:

: 81058-27-7
2,3,4,6-tetra-O-pivaloyl-α-D-glucopyranosyl bromide

: 650635-12-4
(1R)-4-[(3S)-3-hydroxybutyl]-3,5,5-trimethylcyclohex-3-enyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 48 percent / AgOTf; N,N-tetramethylurea; 4A molecular sieves / CH₂Cl₂ / 2.5 h / 0 - 20 °C

2: 95 percent / LiOH*H₂O / methanol / 20 h / 20 °C

3: 74 percent / LiOH*H₂O / methanol / 20 h / Heating

With lithium hydroxide; 4 A molecular sieve; silver trifluoromethanesulfonate; tetramethylurea; In methanol; dichloromethane;
DOI:10.1248/cpb.51.878