(4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

Base Information

Chemical Name:(4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one
CAS No.:910818-47-2
Molecular Formula:C₂₃H₂₁O₄P
Molecular Weight:392.391
Hs Code.:

Synonyms:(4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

Chemical Property:

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Technology Process of (4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

There total 1 articles about (4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₂H₂₃O₃P

: 530-62-1
1,1'-carbonyldiimidazole

: 910818-47-2
(4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

: (4S,5S)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

Guidance literature:: In dichloromethane; at 20 ℃; for 2.5h; Title compound not separated from byproducts.;
DOI:10.1039/b606874j

Reference yield: 87.0%

: 910818-47-2
(4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

: 910818-52-9
(1S,2R)-1-azido-4-diphenylphosphinoyl-1-phenyl-butan-2-ol

Guidance literature:: With sodium azide; water; In N,N-dimethyl-formamide; at 110 ℃; for 48h;
DOI:10.1039/b606874j

Reference yield:

: 910818-47-2
(4R,5R)-4-[2'-(diphenylphosphinoyl)-ethyl]-5-phenyl-[1,3]-dioxolane-2-one

: 910818-86-9
(1'R,2'R,1''R)-{2'-[1''-azido-1''-phenyl)-methyl]-cyclopropyl}-1-phenyl-methanone

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / NaN₃; H₂O / dimethylformamide / 48 h / 110 °C

2: 73 percent / Et₃N; DMAP / CH₂Cl₂ / 19 h

3: LDA / tetrahydrofuran / -78 - 20 °C

With dmap; sodium azide; water; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/b606874j