methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Base Information

Chemical Name:methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate
CAS No.:1190291-17-8
Molecular Formula:C₃₁H₄₉NO₁₀SSi₂
Molecular Weight:683.968
Hs Code.:

Synonyms:methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

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Technology Process of methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

There total 1 articles about methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1190291-23-6
methyl (phenyl 4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

: 108-24-7
acetic anhydride

: 1190291-17-8
methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Guidance literature:: With pyridine; at 0 - 20 ℃; for 10h;
DOI:10.1002/ejoc.200900543

Reference yield:

: 1190291-17-8
methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

: 117253-42-6
2-(trimethylsilyl)ethyl 2,3,6-tri-O-benzyl-4-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranoside

: 1190291-65-6
2-(trimethylsilyl)ethyl (methyl 4,5-N,O-carbonylamino-7-O-acetyl-8,9-O-TIPDS-3,5-dideoxy-D-glycero-β-D-galacto-2-nonulopyranosidonate)-(2->3)-2,6-di-O-benzyl-β-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 1190291-82-7
2-(trimethylsilyl)ethyl (methyl 4,5-N,O-carbonylamino-7-O-acetyl-8,9-O-TIPDS-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosidonate)-(2->3)-2,6-di-O-benzyl-β-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; at -40 ℃; for 0.5h; optical yield given as %de; stereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1002/ejoc.200900543

Reference yield:

: 1190291-17-8
methyl (phenyl 7-O-acetyl-4,5-N,O-carbonylamino-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate

: 159922-50-6
4-methoxyphenyl 2,6-di-O-benzyl-β-D-galactopyranoside

: 1190291-55-4
4-methoxyphenyl (methyl 4,5-N,O-carbonylamino-7-O-acetyl-8,9-O-TIPDS-3,5-dideoxy-D-glycero-β-D-galacto-2-nonulopyranosidonate)-(2->3)-2,6-di-O-benzyl-β-D-galactopyranoside

: 1190291-77-0
4-methoxyphenyl (methyl 4,5-N,O-carbonylamino-7-O-acetyl-8,9-O-TIPDS-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosidonate)-(2->3)-2,6-di-O-benzyl-β-D-galactopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; at -40 ℃; for 0.5h; optical yield given as %de; stereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1002/ejoc.200900543