7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene

Base Information

Chemical Name:7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene
CAS No.:486998-58-7
Molecular Formula:C₉₁H₂₇NO
Molecular Weight:1150.22
Hs Code.:

Synonyms:7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene

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Chemical Property of 7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene

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Technology Process of 7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene

There total 4 articles about 7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0
fullerene-C₆₀

: 486998-57-6
7-α-bromoacetyl-9,9-diethyl-2-diphenylaminofluorene

: 486998-58-7
7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 20 ℃; for 5h; under 760.051 Torr;

Reference yield:

: 1133-80-8
2-bromo-9H-fluorene

: 486998-58-7
7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene

Guidance literature:: Multi-step reaction with 4 steps

1: NaOH; tetrabutylammonium bromide / toluene / 8 h / 60 °C

2: 98 percent / rac-BINAP; t-BuONa / tris(dibenzylideneacetone)dipalladium⁽⁰⁾ / toluene / 8 h / 110 °C

3: 66 percent / AlCl₃ / 1,2-dichloro-ethane / 4 h / 0 - 20 °C

4: 52 percent / DBU / toluene / 5 h / 20 °C

With sodium hydroxide; aluminium trichloride; tetrabutylammomium bromide; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In 1,2-dichloro-ethane; toluene; 3: Friedel-Crafts condensation;
DOI:10.1039/b202681c

Reference yield:

: 287493-15-6
2-bromo-9,9-diethyl-9H-fluorene

: 486998-58-7
7-(1,2-methano[60]fullerene-61-carbonyl)-9,9-diethyl-2-diphenylaminofluorene

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / rac-BINAP; t-BuONa / tris(dibenzylideneacetone)dipalladium⁽⁰⁾ / toluene / 8 h / 110 °C

2: 66 percent / AlCl₃ / 1,2-dichloro-ethane / 4 h / 0 - 20 °C

3: 52 percent / DBU / toluene / 5 h / 20 °C

With aluminium trichloride; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In 1,2-dichloro-ethane; toluene; 2: Friedel-Crafts condensation;
DOI:10.1039/b202681c