C₅₂H₈₇N₅O₉SSi

Base Information

Chemical Name:C₅₂H₈₇N₅O₉SSi
CAS No.:582321-86-6
Molecular Formula:C₅₂H₈₇N₅O₉SSi
Molecular Weight:986.442
Hs Code.:

C<sub>52</sub>H<sub>87</sub>N<sub>5</sub>O<sub>9</sub>SSi

Synonyms:C₅₂H₈₇N₅O₉SSi

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Chemical Property of C₅₂H₈₇N₅O₉SSi

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Technology Process of C₅₂H₈₇N₅O₉SSi

There total 25 articles about C₅₂H₈₇N₅O₉SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15761-39-4,59433-50-0
1-(tert-butoxycarbonyl)-L-proline

: 582321-86-6
C₅₂H₈₇N₅O₉SSi

Guidance literature:: Multi-step reaction with 15 steps

1.1: diisopropylethylamine; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 3 h / 20 °C

1.2: 94 percent / N,N-dimethyl-4-aminopyridine / toluene / 3 h / 20 °C

2.1: 88 percent / tetra-N-butylammonium fluoride / tetrahydrofuran / 5 h / 20 °C

3.1: 4 Angstroem molecular sieves; N-methylmorpholine-N-oxide; tetra-n-propylammonium perruthenate / CH₂Cl₂ / 0.5 h / 20 °C

4.1: dicyclohexylboron chloride; Me₂NEt / diethyl ether / 1.5 h / 0 °C

4.2: diethyl ether / 19 h / -78 - -20 °C

4.3: aq. H₂O₂ / methanol / 3 h / 20 °C

5.1: 196 mg / 2,6-lutidine / CH₂Cl₂ / 2 h / -50 °C

6.1: K₂CO₃ / methanol / 2 h / 20 °C

7.1: 39.3 mg / aq. NaIO₄ / 2-methyl-propan-2-ol / 12 h / 20 °C

8.1: 75.5 mg / Et₃N; diphenylphosphoryl azide / dimethylformamide / 2 h / 20 °C

9.1: 93 percent / 2,6-dichloro-3,5-dicyanoquinone / CH₂Cl₂; aq. phosphate buffer / 1.5 h / 0 - 20 °C / pH 7

10.1: 97 percent / PPh₃; diisopropylazodicarboxylate; diphenylphosphorylazide / tetrahydrofuran / 0.33 h / 0 °C

11.1: HF-pyridine / tetrahydrofuran / 9 h / 20 °C

12.1: 17 mg / 2,6-lutidine / CH₂Cl₂ / 2 h / -78 °C

13.1: 63 percent / PPh₃ / tetrahydrofuran / 12 h / 50 °C

14.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 20 °C

15.1: 6.3 mg / tetra-n-butylammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

With 2,6-dimethylpyridine; sodium periodate; tetrapropylammonium perruthennate; N,N-dimethyl-ethanamine; di-isopropyl azodicarboxylate; 4 A molecular sieve; 2,4,6-trichlorobenzoyl chloride; diphenylphosphoranyl azide; dicyclohexylboron chloride; tetrabutyl ammonium fluoride; 2,6-dichloro-3,5-dicyano-1,4-benzoquinone; potassium carbonate; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; methanol; phosphate buffer; diethyl ether; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol; 10.1: Mitsunobu reaction / 13.1: Staudinger-aza-Wittig reaction;
DOI:10.1021/ja036050w

Reference yield:

: 67760-86-5
(3S)-2,2-dimethyl-5-hexen-3-ol

: 582321-86-6
C₅₂H₈₇N₅O₉SSi

Guidance literature:: Multi-step reaction with 20 steps

1.1: 71 percent / Et₃N; N-methyl-2-chloropyridinium iodide / CH₂Cl₂ / 2.5 h / Heating

2.1: titanium tetra-isopropoxide / CH₂Cl₂ / 1 h / 40 °C

2.2: 97 percent / benzylidene-bis(tricyclohexylphosphine)dichlororuthenium / CH₂Cl₂ / 3 h / Heating

3.1: CuCN / diethyl ether / -78 - 0 °C

3.2: 86 percent / diethyl ether / 1 h / -78 - -25 °C

4.1: 83 percent / LiAlH₄ / diethyl ether / 0.67 h / 0 °C

5.1: 86 percent / imidazole / CH₂Cl₂ / 0.5 h / 20 °C

6.1: diisopropylethylamine; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 3 h / 20 °C

6.2: 94 percent / N,N-dimethyl-4-aminopyridine / toluene / 3 h / 20 °C

7.1: 88 percent / tetra-N-butylammonium fluoride / tetrahydrofuran / 5 h / 20 °C

8.1: 4 Angstroem molecular sieves; N-methylmorpholine-N-oxide; tetra-n-propylammonium perruthenate / CH₂Cl₂ / 0.5 h / 20 °C

9.1: dicyclohexylboron chloride; Me₂NEt / diethyl ether / 1.5 h / 0 °C

9.2: diethyl ether / 19 h / -78 - -20 °C

9.3: aq. H₂O₂ / methanol / 3 h / 20 °C

10.1: 196 mg / 2,6-lutidine / CH₂Cl₂ / 2 h / -50 °C

11.1: K₂CO₃ / methanol / 2 h / 20 °C

12.1: 39.3 mg / aq. NaIO₄ / 2-methyl-propan-2-ol / 12 h / 20 °C

13.1: 75.5 mg / Et₃N; diphenylphosphoryl azide / dimethylformamide / 2 h / 20 °C

14.1: 93 percent / 2,6-dichloro-3,5-dicyanoquinone / CH₂Cl₂; aq. phosphate buffer / 1.5 h / 0 - 20 °C / pH 7

15.1: 97 percent / PPh₃; diisopropylazodicarboxylate; diphenylphosphorylazide / tetrahydrofuran / 0.33 h / 0 °C

16.1: HF-pyridine / tetrahydrofuran / 9 h / 20 °C

17.1: 17 mg / 2,6-lutidine / CH₂Cl₂ / 2 h / -78 °C

18.1: 63 percent / PPh₃ / tetrahydrofuran / 12 h / 50 °C

19.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 20 °C

20.1: 6.3 mg / tetra-n-butylammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

With 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; sodium periodate; lithium aluminium tetrahydride; tetrapropylammonium perruthennate; N,N-dimethyl-ethanamine; di-isopropyl azodicarboxylate; 4 A molecular sieve; 2,4,6-trichlorobenzoyl chloride; diphenylphosphoranyl azide; dicyclohexylboron chloride; tetrabutyl ammonium fluoride; 2-chloro-1-methyl-pyridinium iodide; 2,6-dichloro-3,5-dicyano-1,4-benzoquinone; potassium carbonate; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; methanol; phosphate buffer; diethyl ether; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol; 15.1: Mitsunobu reaction / 18.1: Staudinger-aza-Wittig reaction;
DOI:10.1021/ja036050w

Reference yield:

: 122520-65-4
methyl (2E,4R)-2-methyl-4-hydroxy-5-(t-butyldimethylsilyl)oxypent-2-enoate

: 582321-86-6
C₅₂H₈₇N₅O₉SSi

Guidance literature:: Multi-step reaction with 14 steps

1: 75 percent / trifluoromethanesulfonic acid / diethyl ether / 0.17 h / 20 °C

2: 83 percent / aq. LiOH / 2-methyl-propan-2-ol; tetrahydrofuran / 12 h / 20 °C

3: 69.1 mg / diisopropylethylamine; PyAOP / dimethylformamide / 2 h / 20 °C

4: 98 percent / HF*pyridine / tetrahydrofuran / 0.5 h / 20 °C

5: 85 percent / PPh₃; diisopropylazodicarboxylate / tetrahydrofuran / 0.08 h / 0 °C

6: K₂CO₃ / CH₂Cl₂; methanol / 1 h / 0 °C

7: 75.5 mg / Et₃N; diphenylphosphoryl azide / dimethylformamide / 2 h / 20 °C

8: 93 percent / 2,6-dichloro-3,5-dicyanoquinone / CH₂Cl₂; aq. phosphate buffer / 1.5 h / 0 - 20 °C / pH 7

9: 97 percent / PPh₃; diisopropylazodicarboxylate; diphenylphosphorylazide / tetrahydrofuran / 0.33 h / 0 °C

10: HF-pyridine / tetrahydrofuran / 9 h / 20 °C

11: 17 mg / 2,6-lutidine / CH₂Cl₂ / 2 h / -78 °C

12: 63 percent / PPh₃ / tetrahydrofuran / 12 h / 50 °C

13: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 20 °C

14: 6.3 mg / tetra-n-butylammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

With 2,6-dimethylpyridine; lithium hydroxide; trifluorormethanesulfonic acid; di-isopropyl azodicarboxylate; diphenylphosphoranyl azide; tetrabutyl ammonium fluoride; 2,6-dichloro-3,5-dicyano-1,4-benzoquinone; potassium carbonate; pyridine hydrogenfluoride; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; methanol; phosphate buffer; diethyl ether; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol; 9: Mitsunobu reaction / 12: Staudinger-aza-Wittig reaction;
DOI:10.1021/ja036050w