Technology Process of 6-methyl-3-p-tolylindole
There total 3 articles about 6-methyl-3-p-tolylindole which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
1,10-Phenanthroline; carbon monoxide; palladium diacetate;
In
N,N-dimethyl-formamide;
at 110 ℃;
for 3h;
under 760.051 Torr;
DOI:10.1016/j.tet.2008.11.034
- Guidance literature:
-
Multi-step reaction with 2 steps
1: tert.-butylnitrite; oxygen; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / 1,4-dioxane / 90 °C / Inert atmosphere
2: 1,10-Phenanthroline; palladium diacetate; molybdenum hexacarbonyl / 1,2-dichloro-ethane / 4 h / 120 °C / Inert atmosphere
With
tert.-butylnitrite; 1,10-Phenanthroline; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; palladium diacetate; molybdenum hexacarbonyl;
In
1,4-dioxane; 1,2-dichloro-ethane;
DOI:10.1002/ejoc.202000580
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium tert-butylate / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere
1.2: 2 h / Inert atmosphere
2.1: tert.-butylnitrite; oxygen; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / 1,4-dioxane / 90 °C / Inert atmosphere
3.1: 1,10-Phenanthroline; palladium diacetate; molybdenum hexacarbonyl / 1,2-dichloro-ethane / 4 h / 120 °C / Inert atmosphere
With
tert.-butylnitrite; 1,10-Phenanthroline; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium tert-butylate; oxygen; palladium diacetate; molybdenum hexacarbonyl;
In
tetrahydrofuran; 1,4-dioxane; 1,2-dichloro-ethane;
DOI:10.1002/ejoc.202000580
