benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

Base Information

Chemical Name:benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate
CAS No.:316188-30-4
Molecular Formula:C₅₈H₅₈O₁₄
Molecular Weight:979.09
Hs Code.:

Synonyms:benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

Suppliers and Price of benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

There total 5 articles about benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 316188-27-9
benzyl 2-O-benzoyl-6-O-benzyl-3-O-[1,4-dioxo-4-(phenyl 2,3,6-tri-O-benzyl-1-thio-α-D-mannopyranosid-4-O-yl)butyl]-α-D-glucopyranoside

: 316188-30-4
benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

: 316188-28-0
benzyl O-(2,3,6-tri-O-benzyl-α-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

Guidance literature:: With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; 3 Angstroem MS; In dichloromethane; at -30 ℃;
DOI:10.1002/1522-2675(20001004)83:10<2655::AID-HLCA2655>3.0.CO;2-U

Reference yield:

: 159407-17-7
phenyl 2,3-di-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

: 316188-30-4
benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

Guidance literature:: Multi-step reaction with 5 steps

1: 80 percent / NaCNBH₃; HCl; 3 Angstroem MS / tetrahydrofuran; diethyl ether / 20 °C

2: 82 percent / pyridine; DMAP / 24 h / 60 °C

3: 74 percent / DCC; DMAP / CH₂Cl₂ / 24 h / 20 °C

4: 78 percent / NaCNBH₃; 3 Angstroem MS; HCl / tetrahydrofuran; diethyl ether / 20 °C

5: 7 percent / NIS; Me₃SiOTf; 3 Angstroem MS / acetonitrile / -30 °C

With pyridine; hydrogenchloride; dmap; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; 3 Angstroem MS; sodium cyanoborohydride; dicyclohexyl-carbodiimide; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile; 1: Ring cleavage / 2: Acylation / 3: Acylation / 4: Ring cleavage / 5: Cyclization;
DOI:10.1002/1522-2675(20001004)83:10<2655::AID-HLCA2655>3.0.CO;2-U

Reference yield:

: 316188-24-6
phenyl 2,3,6-tri-O-benzyl-1-thio-α-D-mannopyranoside

: 316188-30-4
benzyl O-(2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1-> 4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside 3,4'-succinate

Guidance literature:: Multi-step reaction with 4 steps

1: 82 percent / pyridine; DMAP / 24 h / 60 °C

2: 74 percent / DCC; DMAP / CH₂Cl₂ / 24 h / 20 °C

3: 78 percent / NaCNBH₃; 3 Angstroem MS; HCl / tetrahydrofuran; diethyl ether / 20 °C

4: 7 percent / NIS; Me₃SiOTf; 3 Angstroem MS / acetonitrile / -30 °C

With pyridine; hydrogenchloride; dmap; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; 3 Angstroem MS; sodium cyanoborohydride; dicyclohexyl-carbodiimide; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile; 1: Acylation / 2: Acylation / 3: Ring cleavage / 4: Cyclization;
DOI:10.1002/1522-2675(20001004)83:10<2655::AID-HLCA2655>3.0.CO;2-U