((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi

Base Information

• Chemical Name: ((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi
• CAS No.: 77617-69-7
• Molecular Formula: C₃₀H₃₆LiNP₂Si₂
• Molecular Weight: 535.682
• Mol file: 77617-69-7.mol

Synonyms:((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi

Chemical Property of ((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of ((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi

There total 1 articles about ((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-bis<(diphenylphosphino)methyl>tetramethyldisilazane (77617-70-0) → ((C6H5)2PCH2Si(CH3)2)2N(1-)*Li(1+)=((C6H5)2PCH2Si(CH3)2)2NLi (77617-69-7)

Guidance literature:

With n-butyllithium; In hexane;

DOI:10.1021/ja00402a067

Reference yield: 91.0%

(PPh3)3RuHCl*PhMe (217661-36-4) + ((C6H5)2PCH2Si(CH3)2)2N(1-)*Li(1+)=((C6H5)2PCH2Si(CH3)2)2NLi (77617-69-7) → ((C6H5)2PCH2Si(CH3)2)2NRuH(P(C6H5)3) (131703-26-9)

Guidance literature:

In toluene; under inert atm., Schlenk flask; stirred at room temp. for 48 h; filtered, volatiles removed to liquid N2 trap, solid powdered in mortar,free PPh3 removed by sublimation (60°C, 0.003 torr, 1 week);

DOI:10.1039/b206202j

Reference yield: 84.0%

((C6H5)2PCH2Si(CH3)2)2N(1-)*Li(1+)=((C6H5)2PCH2Si(CH3)2)2NLi (77617-69-7) + iron(II) chloride → Fe(N(Si(CH3)2CH2P(C6H5)2)2)2 (206666-45-7)

Guidance literature:

In tetrahydrofuran; N2 or Ar-atmosphere; evapn. (vac.), extg. (hexanes), filtering; elem. anal.;

DOI:10.1021/om970665i

upstream raw materials:

1,3-bis<(diphenylphosphino)methyl>tetramethyldisilazane

Downstream raw materials:

C₃₇H₄₁NOP₂Si₂

iridium(η2-C8H14)(N(SiMe2CH2PPh2)2)

NiCl{N(Si(CH₃)2CH₂P(C₆H₅)2)2}

Rh(η2-cyclooctene){N(SiMe2CH2PPh2)2}