C₆₅H₁₁₄O₁₄SSi₄

Base Information

Chemical Name:C₆₅H₁₁₄O₁₄SSi₄
CAS No.:125024-35-3
Molecular Formula:C₆₅H₁₁₄O₁₄SSi₄
Molecular Weight:1264.02
Hs Code.:

C<sub>65</sub>H<sub>114</sub>O<sub>14</sub>SSi<sub>4</sub>

Synonyms:C₆₅H₁₁₄O₁₄SSi₄

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Chemical Property of C₆₅H₁₁₄O₁₄SSi₄

Chemical Property:

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Technology Process of C₆₅H₁₁₄O₁₄SSi₄

There total 31 articles about C₆₅H₁₁₄O₁₄SSi₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6742-53-6,10150-93-3,200628-30-4
(E)-ethyl 4-oxo-2-pentenoate

: 125024-35-3
C₆₅H₁₁₄O₁₄SSi₄

Guidance literature:: Multi-step reaction with 22 steps

1: p-TsOH / benzene / Heating

2: 74 percent / (i-Bu)2AlH / toluene / 1 h / -78 °C

3: 90 percent / PhCMe₂O₂H, (-)-DIPT, Ti(O-i-Pr)4, 4A molecular sieves / CH₂Cl₂ / 22 h / -20 °C

4: 71 percent / diethyl ether / 0 - 25 °C

5: 90 percent / py-DMAP / CH₂Cl₂ / 2 h / 25 °C

6: 86 percent / pyridinium p-toluenesulfonate (PPTS) / H₂O; tetrahydrofuran / 36 h / 50 °C

7: 93 percent / (i-Pr)2NEt / CH₂Cl₂ / 4 h / Heating

8: 85 percent / LDA / tetrahydrofuran / 0.5 h / -78 °C

9: 1.) Ac₂O, Et₃N, DMAP, 2.) DBU / 1.) CH₂Cl₂, 25 deg, 2 h, 2.) 25 deg C, 1 h

10: 93 percent / tetrahydrofuran / 1 h / 0 °C

11: 87 percent / Et₃N / CH₂Cl₂ / -78 - 25 °C

12: 90 percent / 2KHSO₅*KHSO₄*K₂SO₄ (Oxone) / methanol; H₂O / 48 h / 25 °C

13: 92 percent / (NH₄)2Ce(NO₃)6 / acetonitrile; H₂O / 1 h / 25 °C

14: 82 percent / 2,6-lutidine / CH₂Cl₂ / 0 °C

15: 77 percent / LiAlH₄ / tetrahydrofuran / 0 °C

16: 35 percent / 2.5percent Na(Hg), Na₂HPO₄ / methanol / 2 h / 25 °C

17: 90 percent / (COCl)2, Et₃N / dimethylsulfoxide; CH₂Cl₂ / -78 - 25 °C

18: 98 percent / toluene / 2 h / Heating

19: 94 percent / (i-Bu)2AlH / toluene / 0.5 h / -75 °C

20: 93 percent / N-chlorosuccinimide, Me₂S / CH₂Cl₂ / 0.5 h / 0 - 25 °C

21: 84 percent / dimethylformamide / 48 h / 25 °C

22: 1.) n-BuLi / 1.) THF, -78 deg C, 0.5 h

With 2,6-dimethylpyridine; titanium(IV) isopropylate; dmap; potassium sulfate; potassium hydrogensulfate; disodium hydrogenphosphate; N-chloro-succinimide; lithium aluminium tetrahydride; potassium peroxomonosulfate; n-butyllithium; sodium amalgam; oxalyl dichloride; ammonium cerium(IV) nitrate; dimethylsulfide; Cumene hydroperoxide; 4-(dimethylamino)pyridine in pyridine; 4 A molecular sieve; pyridinium p-toluenesulfonate; acetic anhydride; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; acetonitrile; benzene;
DOI:10.1021/ja00160a051

Reference yield:

: 125048-91-1
(1S,2R)-2-(1,3-dihydroxy-2-methylpropyl)-2,5,5-trimethyl-1,3-dioxane

: 125024-35-3
C₆₅H₁₁₄O₁₄SSi₄

Guidance literature:: Multi-step reaction with 18 steps

1: 90 percent / py-DMAP / CH₂Cl₂ / 2 h / 25 °C

2: 86 percent / pyridinium p-toluenesulfonate (PPTS) / H₂O; tetrahydrofuran / 36 h / 50 °C

3: 93 percent / (i-Pr)2NEt / CH₂Cl₂ / 4 h / Heating

4: 85 percent / LDA / tetrahydrofuran / 0.5 h / -78 °C

5: 1.) Ac₂O, Et₃N, DMAP, 2.) DBU / 1.) CH₂Cl₂, 25 deg, 2 h, 2.) 25 deg C, 1 h

6: 93 percent / tetrahydrofuran / 1 h / 0 °C

7: 87 percent / Et₃N / CH₂Cl₂ / -78 - 25 °C

8: 90 percent / 2KHSO₅*KHSO₄*K₂SO₄ (Oxone) / methanol; H₂O / 48 h / 25 °C

9: 92 percent / (NH₄)2Ce(NO₃)6 / acetonitrile; H₂O / 1 h / 25 °C

10: 82 percent / 2,6-lutidine / CH₂Cl₂ / 0 °C

11: 77 percent / LiAlH₄ / tetrahydrofuran / 0 °C

12: 35 percent / 2.5percent Na(Hg), Na₂HPO₄ / methanol / 2 h / 25 °C

13: 90 percent / (COCl)2, Et₃N / dimethylsulfoxide; CH₂Cl₂ / -78 - 25 °C

14: 98 percent / toluene / 2 h / Heating

15: 94 percent / (i-Bu)2AlH / toluene / 0.5 h / -75 °C

16: 93 percent / N-chlorosuccinimide, Me₂S / CH₂Cl₂ / 0.5 h / 0 - 25 °C

17: 84 percent / dimethylformamide / 48 h / 25 °C

18: 1.) n-BuLi / 1.) THF, -78 deg C, 0.5 h

With 2,6-dimethylpyridine; dmap; potassium sulfate; potassium hydrogensulfate; disodium hydrogenphosphate; N-chloro-succinimide; lithium aluminium tetrahydride; potassium peroxomonosulfate; n-butyllithium; sodium amalgam; oxalyl dichloride; ammonium cerium(IV) nitrate; dimethylsulfide; 4-(dimethylamino)pyridine in pyridine; pyridinium p-toluenesulfonate; acetic anhydride; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1021/ja00160a051

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 125024-35-3
C₆₅H₁₁₄O₁₄SSi₄

Guidance literature:: Multi-step reaction with 9 steps

1: 82 percent / 2,6-lutidine / CH₂Cl₂ / 0 °C

2: 77 percent / LiAlH₄ / tetrahydrofuran / 0 °C

3: 35 percent / 2.5percent Na(Hg), Na₂HPO₄ / methanol / 2 h / 25 °C

4: 90 percent / (COCl)2, Et₃N / dimethylsulfoxide; CH₂Cl₂ / -78 - 25 °C

5: 98 percent / toluene / 2 h / Heating

6: 94 percent / (i-Bu)2AlH / toluene / 0.5 h / -75 °C

7: 93 percent / N-chlorosuccinimide, Me₂S / CH₂Cl₂ / 0.5 h / 0 - 25 °C

8: 84 percent / dimethylformamide / 48 h / 25 °C

9: 1.) n-BuLi / 1.) THF, -78 deg C, 0.5 h

With 2,6-dimethylpyridine; disodium hydrogenphosphate; N-chloro-succinimide; lithium aluminium tetrahydride; n-butyllithium; sodium amalgam; oxalyl dichloride; dimethylsulfide; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja00160a051