tris(benzyloxymethyl)methyl diazoacetate

Base Information

Chemical Name:tris(benzyloxymethyl)methyl diazoacetate
CAS No.:863642-56-2
Molecular Formula:C₂₇H₂₈N₂O₅
Molecular Weight:460.53
Hs Code.:

Synonyms:tris(benzyloxymethyl)methyl diazoacetate

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Chemical Property of tris(benzyloxymethyl)methyl diazoacetate

Chemical Property:

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Technology Process of tris(benzyloxymethyl)methyl diazoacetate

There total 3 articles about tris(benzyloxymethyl)methyl diazoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3-oxo-butyric acid 2-benzyloxy-1,1-bis-benzyloxymethyl-ethyl ester

: 863642-56-2
tris(benzyloxymethyl)methyl diazoacetate

Guidance literature:: 3-oxo-butyric acid 2-benzyloxy-1,1-bis-benzyloxymethyl-ethyl ester; With triethylamine; Methanesulfonyl azide; In acetonitrile; for 24h;

With lithium hydroxide; In acetonitrile; for 24h;
DOI:10.1021/ja0524043

Reference yield:

: 3587-60-8
Benzyloxymethyl chloride

: 863642-56-2
tris(benzyloxymethyl)methyl diazoacetate

Guidance literature:: Multi-step reaction with 3 steps

1.1: Mg; HgCl₂; I₂ / tetrahydrofuran / Heating

1.2: 37 percent / tetrahydrofuran / 24 h / 22 °C

2.1: DMAP / diethyl ether / 2.5 h / 22 °C

3.1: methanesulfonyl azide; Et₃N / acetonitrile / 24 h

3.2: 0.559 g / aq. LiOH / acetonitrile / 24 h

With dmap; iodine; magnesium; triethylamine; Methanesulfonyl azide; mercury dichloride; In tetrahydrofuran; diethyl ether; acetonitrile;
DOI:10.1021/ja0524043

Reference yield:

: 14869-33-1
tris(benzyloxymethyl)carbinol

: 863642-56-2
tris(benzyloxymethyl)methyl diazoacetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: DMAP / diethyl ether / 2.5 h / 22 °C

2.1: methanesulfonyl azide; Et₃N / acetonitrile / 24 h

2.2: 0.559 g / aq. LiOH / acetonitrile / 24 h

With dmap; triethylamine; Methanesulfonyl azide; In diethyl ether; acetonitrile;
DOI:10.1021/ja0524043