C₃₅H₄₄O₆Si

Base Information

• Chemical Name: C₃₅H₄₄O₆Si
• CAS No.: 301823-99-4
• Molecular Formula: C₃₅H₄₄O₆Si
• Molecular Weight: 588.816

Synonyms:C₃₅H₄₄O₆Si

Chemical Property of C₃₅H₄₄O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₅H₄₄O₆Si

There total 24 articles about C₃₅H₄₄O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(-)-(1R,5S,7S)-3-[(1R)-2-hydroxy-1-phenylethyl]-6,6-dimethyl-10-oxa-3-azatricyclo[5.2.1.01,5]dec-8-en-4-one (77704-39-3) → C35H44O6Si (301823-99-4)

Guidance literature:

Multi-step reaction with 22 steps

1.1: pyridine / CH₂Cl₂

2.1: DBU / acetonitrile

2.2: aq. HCl

3.1: NaNO₂; Ac₂O / acetic acid

4.1: KOH

5.1: p-TsOH / CH₂Cl₂

6.1: disiamylborane / tetrahydrofuran

6.2: aq. H₂O₂; NaOH

7.1: imidazole / CH₂Cl₂

8.1: LiAlH₄ / tetrahydrofuran

9.1: TPAP; NMO / acetone

10.1: tetrahydrofuran

11.1: aq. AcOH / tetrahydrofuran

12.1: SO₃; pyridine; Et₃N / dimethylsulfoxide; CH₂Cl₂

13.1: CrCl₂ / NiCl₂ / dimethylformamide / 50 °C

14.1: LiAlH₄ / diethyl ether

15.1: pyridine / CH₂Cl₂

16.1: pyridine / CH₂Cl₂

17.1: CSA / methanol

18.1: TPAP; NMO / acetone

19.1: tetrahydrofuran

20.1: 99 percent / Grubbs' ruthenium benzylidene catalyst / toluene / 16 h / Heating

21.1: OsO₄; DMAP / 2-methyl-propan-2-ol; H₂O

22.1: Dess-Martin periodinane / CH₂Cl₂

With pyridine; 1H-imidazole; chromium dichloride; dmap; potassium hydroxide; osmium(VIII) oxide; lithium aluminium tetrahydride; N-methyl-2-indolinone; tetrapropylammonium perruthennate; camphor-10-sulfonic acid; sulfur trioxide; bis-(1,2-dimethylpropyl)borane; acetic anhydride; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; sodium nitrite; Grubbs catalyst first generation; nickel dichloride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol; 1.1: Etherification / 2.1: Elimination / 2.2: Hydrolysis / 3.1: Nitrosation / 4.1: Ring cleavage / 5.1: Addition / 6.1: Hydroboration / 6.2: Oxidation / 7.1: Etherification / 8.1: Reduction / 9.1: Oxidation / 10.1: Wittig olefination / 11.1: Substitution / 12.1: Oxidation / 13.1: Condensation / 14.1: Reduction / 15.1: Etherification / 16.1: Acetylation / 17.1: Substitution / 18.1: Oxidation / 19.1: Wittig olefination / 20.1: Cyclization / 21.1: Addition / 22.1: Oxidation;

DOI:10.1039/b003757p

Reference yield:

(-)-(R)-N-<(Furan-2-yl)methyl>-N-(2-hyydroxy-1-phenylethyl)-3-methylbut-2-enamid (77704-70-2) → C35H44O6Si (301823-99-4)

Guidance literature:

Multi-step reaction with 23 steps

1.1: n-BuMgCl / diethyl ether / -60 °C

1.2: toluene / 16 h / Heating

2.1: pyridine / CH₂Cl₂

3.1: DBU / acetonitrile

3.2: aq. HCl

4.1: NaNO₂; Ac₂O / acetic acid

5.1: KOH

6.1: p-TsOH / CH₂Cl₂

7.1: disiamylborane / tetrahydrofuran

7.2: aq. H₂O₂; NaOH

8.1: imidazole / CH₂Cl₂

9.1: LiAlH₄ / tetrahydrofuran

10.1: TPAP; NMO / acetone

11.1: tetrahydrofuran

12.1: aq. AcOH / tetrahydrofuran

13.1: SO₃; pyridine; Et₃N / dimethylsulfoxide; CH₂Cl₂

14.1: CrCl₂ / NiCl₂ / dimethylformamide / 50 °C

15.1: LiAlH₄ / diethyl ether

16.1: pyridine / CH₂Cl₂

17.1: pyridine / CH₂Cl₂

18.1: CSA / methanol

19.1: TPAP; NMO / acetone

20.1: tetrahydrofuran

21.1: 99 percent / Grubbs' ruthenium benzylidene catalyst / toluene / 16 h / Heating

22.1: OsO₄; DMAP / 2-methyl-propan-2-ol; H₂O

23.1: Dess-Martin periodinane / CH₂Cl₂

With pyridine; 1H-imidazole; chromium dichloride; dmap; potassium hydroxide; osmium(VIII) oxide; lithium aluminium tetrahydride; N-methyl-2-indolinone; tetrapropylammonium perruthennate; camphor-10-sulfonic acid; sulfur trioxide; butyl magnesium bromide; bis-(1,2-dimethylpropyl)borane; acetic anhydride; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; sodium nitrite; Grubbs catalyst first generation; nickel dichloride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol; 1.1: Metallation / 1.2: Cyclization / 2.1: Etherification / 3.1: Elimination / 3.2: Hydrolysis / 4.1: Nitrosation / 5.1: Ring cleavage / 6.1: Addition / 7.1: Hydroboration / 7.2: Oxidation / 8.1: Etherification / 9.1: Reduction / 10.1: Oxidation / 11.1: Wittig olefination / 12.1: Substitution / 13.1: Oxidation / 14.1: Condensation / 15.1: Reduction / 16.1: Etherification / 17.1: Acetylation / 18.1: Substitution / 19.1: Oxidation / 20.1: Wittig olefination / 21.1: Cyclization / 22.1: Addition / 2;

DOI:10.1039/b003757p

Reference yield:

(+)-(1R,5S,7S)-6,6-dimethyl-10-oxa-3-azatricyclo[5.2.1.o1,5]dec-8-en-4-one (301823-95-0) → C35H44O6Si (301823-99-4)

Guidance literature:

Multi-step reaction with 20 steps

1.1: NaNO₂; Ac₂O / acetic acid

2.1: KOH

3.1: p-TsOH / CH₂Cl₂

4.1: disiamylborane / tetrahydrofuran

4.2: aq. H₂O₂; NaOH

5.1: imidazole / CH₂Cl₂

6.1: LiAlH₄ / tetrahydrofuran

7.1: TPAP; NMO / acetone

8.1: tetrahydrofuran

9.1: aq. AcOH / tetrahydrofuran

10.1: SO₃; pyridine; Et₃N / dimethylsulfoxide; CH₂Cl₂

11.1: CrCl₂ / NiCl₂ / dimethylformamide / 50 °C

12.1: LiAlH₄ / diethyl ether

13.1: pyridine / CH₂Cl₂

14.1: pyridine / CH₂Cl₂

15.1: CSA / methanol

16.1: TPAP; NMO / acetone

17.1: tetrahydrofuran

18.1: 99 percent / Grubbs' ruthenium benzylidene catalyst / toluene / 16 h / Heating

19.1: OsO₄; DMAP / 2-methyl-propan-2-ol; H₂O

20.1: Dess-Martin periodinane / CH₂Cl₂

With pyridine; 1H-imidazole; chromium dichloride; dmap; potassium hydroxide; osmium(VIII) oxide; lithium aluminium tetrahydride; N-methyl-2-indolinone; tetrapropylammonium perruthennate; camphor-10-sulfonic acid; sulfur trioxide; bis-(1,2-dimethylpropyl)borane; acetic anhydride; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; triethylamine; sodium nitrite; Grubbs catalyst first generation; nickel dichloride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; 1.1: Nitrosation / 2.1: Ring cleavage / 3.1: Addition / 4.1: Hydroboration / 4.2: Oxidation / 5.1: Etherification / 6.1: Reduction / 7.1: Oxidation / 8.1: Wittig olefination / 9.1: Substitution / 10.1: Oxidation / 11.1: Condensation / 12.1: Reduction / 13.1: Etherification / 14.1: Acetylation / 15.1: Substitution / 16.1: Oxidation / 17.1: Wittig olefination / 18.1: Cyclization / 19.1: Addition / 20.1: Oxidation;

DOI:10.1039/b003757p

upstream raw materials:

(-)-(R)-N-<(Furan-2-yl)methyl>-N-(2-hyydroxy-1-phenylethyl)-3-methylbut-2-enamid

(-)-(1R,5S,7S)-3-[(1R)-2-hydroxy-1-phenylethyl]-6,6-dimethyl-10-oxa-3-azatricyclo[5.2.1.0^1,5]dec-8-en-4-one

(+)-(1R,5S,7S)-6,6-dimethyl-10-oxa-3-azatricyclo[5.2.1.o^1,5]dec-8-en-4-one

(1R,2S,4S)-1-hydroxymethyl-3,3-dimethyl-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester

Downstream raw materials:

C₃₅H₄₂O₆Si

C₃₆H₄₄O₆Si

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 301823-99-4 C₃₅H₄₄O₆Si

Send

Send

Metric Ton KG G Pound L ML

Send

Send