2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate

Base Information

Chemical Name:2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate
CAS No.:790230-29-4
Molecular Formula:C₃₃H₃₇NO₆
Molecular Weight:543.66
Hs Code.:

Synonyms:2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate

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Chemical Property of 2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate

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Technology Process of 2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate

There total 10 articles about 2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 790230-26-1
2'-benzyl 2-tert-butyl 4-methyl 4'-aminobiphenyl-2,2',4-tricarboxylate

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 790230-29-4
2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate

Guidance literature:: With sodium tris(acetoxy)borohydride; acetic acid; at 20 ℃; for 24h;
DOI:10.1016/j.bmc.2006.09.071

Reference yield:

: 576170-38-2
3-(tert-butyl) 1-methyl 4-hydroxyisophthalate

: 790230-29-4
2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1.1: 13.3 g / pyridine / CH₂Cl₂ / 0.5 h / 20 °C

2.1: bis(pinacolato)diboron; PPh₃; AcOK / PdCl₂(PPh₃)2 / toluene / Heating

2.2: 74 percent / Na₂CO₃ / Pd(PPh₃)2 / toluene / Heating

3.1: 72 percent / Fe; AcOH / 1 h / 60 °C

4.1: 89 percent / NaBH(OAc)3; AcOH / 24 h / 20 °C

With pyridine; potassium acetate; sodium tris(acetoxy)borohydride; iron; acetic acid; triphenylphosphine; bis(pinacol)diborane; bis-triphenylphosphine-palladium(II) chloride; In dichloromethane; toluene; 2.2: Suzuki coupling;
DOI:10.1016/j.bmc.2006.09.071

Reference yield:

: 790230-23-8
3-tert-butyl 1-methyl 4-{[(trifluoromethyl)sulfonyl]oxy}isophthalate

: 790230-29-4
2'-benzyl 2-tert-butyl 4-methyl 4'-(cyclohexylamino)biphenyl-2,2',4-tricarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: bis(pinacolato)diboron; PPh₃; AcOK / PdCl₂(PPh₃)2 / toluene / Heating

1.2: 74 percent / Na₂CO₃ / Pd(PPh₃)2 / toluene / Heating

2.1: 72 percent / Fe; AcOH / 1 h / 60 °C

3.1: 89 percent / NaBH(OAc)3; AcOH / 24 h / 20 °C

With potassium acetate; sodium tris(acetoxy)borohydride; iron; acetic acid; triphenylphosphine; bis(pinacol)diborane; bis-triphenylphosphine-palladium(II) chloride; In toluene; 1.2: Suzuki coupling;
DOI:10.1016/j.bmc.2006.09.071