C₂₆H₃₂O₃Si

Base Information

• Chemical Name: C₂₆H₃₂O₃Si
• CAS No.: 1093435-71-2
• Molecular Formula: C₂₆H₃₂O₃Si
• Molecular Weight: 420.624
• Mol file: 1093435-71-2.mol

Synonyms:C₂₆H₃₂O₃Si

Chemical Property of C₂₆H₃₂O₃Si

Chemical Property:

Purity/Quality:

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Technology Process of C₂₆H₃₂O₃Si

There total 1 articles about C₂₆H₃₂O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

C23H30O2Si (1093435-69-8) + acryloyl chloride (814-68-6,25189-84-8) → C26H32O3Si (1093435-71-2)

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; at -78 ℃;

DOI:10.1055/s-0028-1083497

Reference yield: 67.0%

C26H32O3Si (1093435-71-2) → (E)-5-[(tert-butyldiphenylsilyloxy)propylidene]-5,6-dihydropyran-2-one (1093435-78-9) + 4-tert-butyldiphenylsilyloxy-1-butene (135006-32-5) + 5-methylene-5,6-dihydro-2H-pyran-2-one (88891-50-3)

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 2h; stereoselective reaction; Reflux;

DOI:10.1055/s-0028-1083497

upstream raw materials:

C₂₃H₃₀O₂Si

acryloyl chloride

Downstream raw materials:

(E)-5-[(tert-butyldiphenylsilyloxy)propylidene]-5,6-dihydropyran-2-one

4-tert-butyldiphenylsilyloxy-1-butene

5-methylene-5,6-dihydro-2H-pyran-2-one

Refernces