2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate)

Base Information

• Chemical Name: 2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate)
• CAS No.: 103725-98-0
• Molecular Formula: C₃₃H₃₇O₁₄PS
• Molecular Weight: 720.688
• Mol file: 103725-98-0.mol

Synonyms:2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate)

Chemical Property of 2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate)

There total 1 articles about 2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2,3,4-tri-O-acetyl-6-O-(p-toluenesulfonyl)-α-D-glucopyranosyl bromide (55500-08-8) + silver dibenzylphosphate (50651-75-7) → 2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate) (103725-98-0)

Guidance literature:

With calcium sulfate; In benzene; for 1.5h; Heating;

DOI:10.1016/S0008-6215(00)90641-4

Reference yield: 67.0%

2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate) (103725-98-0) → 2,3,4-tri-O-acetyl-6-azido-6-deoxy-β-D-glucopyranose 1-(benzyl hydrogen phosphate)

Guidance literature:

With sodium azide; In N,N-dimethyl-formamide; at 80 ℃; for 4h;

DOI:10.1016/S0008-6215(00)90641-4

Reference yield: 51.0%

2,3,4-tri-O-acetyl-6-O-tosyl-β-D-glucopyranose 1-(dibenzyl phosphate) (103725-98-0) → 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-β-D-glucopyranose 1-(benzyl hydrogen phosphate) (103726-07-4)

Guidance literature:

With sodium iodide; In butanone; for 6h; Heating;

DOI:10.1016/S0008-6215(00)90641-4

upstream raw materials:

2,3,4-tri-O-acetyl-6-O-(p-toluenesulfonyl)-α-D-glucopyranosyl bromide

silver dibenzylphosphate

Downstream raw materials:

2,3,4-tri-O-acetyl-6-deoxy-6-iodo-β-D-glucopyranose 1-(benzyl hydrogen phosphate)