diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate

Base Information

Chemical Name:diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate
CAS No.:1620657-23-9
Molecular Formula:C₁₃H₁₉O₄P
Molecular Weight:272.249
Hs Code.:

Synonyms:diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate

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Chemical Property of diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate

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Technology Process of diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate

There total 2 articles about diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 10568-31-7
<αα-2H2>cinnamyl alcohol

: 814-49-3
diethyl chlorophosphate

: 1620657-23-9
diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate

Guidance literature:: With pyridine; dmap; In dichloromethane; at 0 - 20 ℃; for 14h;
DOI:10.1002/anie.201403726

Reference yield:

: 102-92-1,17082-09-6
Cinnamoyl chloride

: 1620657-23-9
diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium borodeuteride / tetrahydrofuran; d⁽⁴⁾-methanol / 1.5 h / 20 °C

2: pyridine; dmap / dichloromethane / 14 h / 0 - 20 °C

With pyridine; dmap; sodium borodeuteride; In tetrahydrofuran; dichloromethane; d⁽⁴⁾-methanol;
DOI:10.1002/anie.201403726

Reference yield:

: 1620657-23-9
diethyl (E)-1,1-bis(deuterio)-3-phenyl-2-propenylphosphate

: 1620657-45-5
2,2-bisdeuterio-3,3-diphenylpropanol

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium hexamethylsilazane / tetrahydrofuran / 3 h / 0 °C

2.1: tetrafluoroboric acid diethyl ether / dichloromethane / 3 h / 0 °C

2.2: 0.25 h / 0 °C

2.3: 14 h / 20 °C

With tetrafluoroboric acid diethyl ether; potassium hexamethylsilazane; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.201403726