5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc

Base Information

• Chemical Name: 5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc
• CAS No.: 1372135-67-5
• Molecular Formula: C₄₈H₃₅N₇Zn
• Molecular Weight: 775.243
• Mol file: 1372135-67-5.mol

Synonyms:5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc

Chemical Property of 5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc

There total 3 articles about 5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

4-(azidomethyl)benzaldehyde (510772-10-8) + zinc(II) acetate dihydrate (5970-45-6) + 4-methyl-benzaldehyde (104-87-0) + 5-(4-methylphenyl)dipyrromethane (147804-55-5) → 5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc (1372135-67-5)

Guidance literature:

With BF₃*Et₂O; p-chloranil; In dichloromethane; 4-azidomethylbenzaldehyde (15.9 mmol), 5-p-tolyldipyrromethane (21.2 mmol), and p-tolylaldehyde (5.2 mmol) in DCM, stirred for 15 min, BF3*Et2O (4 mmol) added, stirred for 1.5 h, p-chloranil (10.5 mmol), stirred for 2 h, evapd., dissolved (DCM/MeOH); evapd., chromd. (SiO2, DCM/heptane=7/3, v/v), elem. anal.;

Reference yield:

C48H37N7 → 5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc (1372135-67-5)

Guidance literature:

With sodium acetate; zinc(II) acetate dihydrate; In methanol; chloroform; for 2h; Reflux;

DOI:10.1021/jp300415a

Reference yield:

4-(azidomethyl)benzaldehyde (510772-10-8) + 4-methyl-benzaldehyde (104-87-0) + 5-(4-methylphenyl)dipyrromethane (147804-55-5) → 5-(4-(azidomethyl)phenyl)-10,15,20-tritolylporphyrin zinc (1372135-67-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: chloroform / 0.25 h / Inert atmosphere

1.2: 1.5 h / Inert atmosphere

1.3: 2 h

2.1: sodium acetate; zinc(II) acetate dihydrate / methanol; chloroform / 2 h / Reflux

With sodium acetate; zinc(II) acetate dihydrate; In methanol; chloroform;

DOI:10.1021/jp300415a

upstream raw materials:

4-(azidomethyl)benzaldehyde

zinc(II) acetate dihydrate

4-methyl-benzaldehyde

5-(4-methylphenyl)dipyrromethane