[7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate

Base Information

Chemical Name:[7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate
CAS No.:1064662-68-5
Molecular Formula:C₁₆H₁₅NO₇S
Molecular Weight:365.364
Hs Code.:

Synonyms:[7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate

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Chemical Property of [7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate

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Technology Process of [7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate

There total 2 articles about [7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 98-59-9
p-toluenesulfonyl chloride

: 59987-31-4
(7-nitro-2,3-dihydrobenzo[b][1,4]dioxin-2-yl)methanol

: 1064662-68-5
[7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate

Guidance literature:: With pyridine; at 5 ℃; for 1h;

Reference yield:

: 3316-09-4
1,2-dihydroxy-4-nitrobenzene

: 1064662-68-5
[7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydrogencarbonate / N,N-dimethyl-formamide / 8.25 h / 4 - 80 °C

2: pyridine / 3 h / 4 - 20 °C

With pyridine; sodium hydrogencarbonate; In N,N-dimethyl-formamide;
DOI:10.1016/j.ejmech.2016.03.068

Reference yield: 59.0%

: 951122-37-5
2,6-difluoro-3-hydroxy-benzamide

: 1064662-68-5
[7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate

: C₁₆H₁₂F₂N₂O₆

Guidance literature:: 2,6-difluoro-3-hydroxy-benzamide; With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 0.25h;

[7-nitro-2,3-dihydro-1,4-benzodioxin-2-yl]methyl 4-methylbenzenesulfonate; In N,N-dimethyl-formamide; at 75 ℃; for 5h;
DOI:10.1016/j.ejmech.2016.03.068