10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

Base Information

Chemical Name:10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one
CAS No.:423772-64-9
Molecular Formula:C₆₂H₁₀₆O₁₃SSi
Molecular Weight:1119.67
Hs Code.:

10-(<i>tert</i>-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

Synonyms:10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

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Chemical Property of 10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

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Technology Process of 10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

There total 4 articles about 10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 423771-84-0
9-(tert-butyl-dimethyl-silanyloxy)-29-(3,4-dimethoxy-benzyloxymethoxy)-23,25-dihydroxy-13,19-dimethoxy-30-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-8,10,17,24,26-pentamethyl-7-methylsulfanylmethoxy-hentriaconta-2,4,14,20-tetraenoic acid

: 423771-85-1
10-(tert-butyl-dimethyl-silanyloxy)-24-[6-(3,4-dimethoxy-benzyloxymethoxy)-2-hydroxy-7-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1,3-dimethyl-octyl]-14,20-dimethoxy-9,11,18-trimethyl-8-methylsulfanylmethoxy-oxacyclotetracosa-3,5,15,21-tetraen-2-one

: 423772-64-9
10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

Guidance literature:: With dmap; 2,4,6-trichlorobenzoyl chloride; triethylamine; In dichloromethane; at 20 ℃; for 2.5h;
DOI:10.1016/S0040-4020(01)01206-6

Reference yield:

: 423771-83-9
9-(tert-butyl-dimethyl-silanyloxy)-29-(3,4-dimethoxy-benzyloxymethoxy)-23,25-dihydroxy-13,19-dimethoxy-30-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-8,10,17,24,26-pentamethyl-7-methylsulfanylmethoxy-hentriaconta-2,4,14,20-tetraenoic acid ethyl ester

: 423772-64-9
10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / LiOH / methanol; H₂O / 13.5 h / 20 °C

2: 31 percent / Et₃N; DMAP; 2,4,6-trichlorobenzoyl chloride / CH₂Cl₂ / 2.5 h / 20 °C

With dmap; lithium hydroxide; 2,4,6-trichlorobenzoyl chloride; triethylamine; In methanol; dichloromethane; water;
DOI:10.1016/S0040-4020(01)01206-6

Reference yield:

: 423771-79-3
C₇₅H₁₄₂O₁₄SSi₃

: 423772-64-9
10-(tert-butyl-dimethyl-silanyloxy)-26-[4-(3,4-dimethoxy-benzyloxymethoxy)-5-(5-methoxy-3-methyl-tetrahydro-furan-2-yl)-1-methyl-hexyl]-24-hydroxy-14,20-dimethoxy-9,11,18,25-tetramethyl-8-methylsulfanylmethoxy-oxacyclohexacosa-3,5,15,21-tetraen-2-one

Guidance literature:: Multi-step reaction with 6 steps

1: 99 percent / DIBAL / CH₂Cl₂; hexane / 1 h / -78 °C

2: 91 percent / C₆H₄(COO)I(OAc)3; pyridine / CH₂Cl₂ / 0.25 h / 20 °C

3: 88 percent / LDA / tetrahydrofuran / 0.42 h / -48 - 20 °C

4: 99 percent / HF-pyridine; pyridine / tetrahydrofuran / 1 h / 20 °C

5: 99 percent / LiOH / methanol; H₂O / 13.5 h / 20 °C

6: 31 percent / Et₃N; DMAP; 2,4,6-trichlorobenzoyl chloride / CH₂Cl₂ / 2.5 h / 20 °C

With pyridine; dmap; lithium hydroxide; C₆H₄(COO)I(OAc)3; 2,4,6-trichlorobenzoyl chloride; diisobutylaluminium hydride; pyridine hydrogenfluoride; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; hexane; dichloromethane; water;
DOI:10.1016/S0040-4020(01)01206-6