Au(Spy)(PPh₂py)

Base Information

• Chemical Name: Au(Spy)(PPh₂py)
• CAS No.: 316802-86-5
• Molecular Formula: C₂₂H₁₈AuN₂PS
• Molecular Weight: 570.405
• Mol file: 316802-86-5.mol

Synonyms:Au(Spy)(PPh₂py)

Chemical Property of Au(Spy)(PPh₂py)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of Au(Spy)(PPh₂py)

There total 3 articles about Au(Spy)(PPh₂py) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2-Sulfanylpyridine (2637-34-5,73018-10-7) + chloro(dimethylsulfide) gold(I) (29892-37-3) + 2-(diphenylphosphino)pyridine (37943-90-1) → Au(Spy)(PPh2py) (316802-86-5)

Guidance literature:

With NaOMe; In methanol; dichloromethane; PPh2py was added to soln. Au(SMe2)Cl in CH2Cl2, after 10 min stirring, soln. predissolved 2-pyridinethiol and NaOMe in MeOH was added dropwise,soln. was stirred for 1 h; solvent was removed by rotary evapn., residue was extd. with CH2Cl2, soln. was concd., pentane was added, ppt. was filtered, washed with Et2O; elem. anal.;

DOI:10.1021/ic000396f

Reference yield:

2-Sulfanylpyridine (2637-34-5,73018-10-7) → Au(Spy)(PPh2py) (316802-86-5)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide / ethanol / 0.25 h / Inert atmosphere; Schlenk technique

2: ethanol / 2 h / 20 °C / Inert atmosphere; Schlenk technique

With potassium hydroxide; In ethanol;

DOI:10.1039/c9nj02502b

Reference yield:

[diphenyl(2-pyridyl)phosphine]gold(I) chloride (38255-48-0) + 2-mercaptopyridine potassium salt (79236-86-5) → Au(Spy)(PPh2py) (316802-86-5)

Guidance literature:

In ethanol; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c9nj02502b

upstream raw materials:

2-Sulfanylpyridine

chloro(dimethylsulfide) gold(I)

2-(diphenylphosphino)pyridine

[diphenyl(2-pyridyl)phosphine]gold(I) chloride

Downstream raw materials:

[AuCu(P(p-tolyl)3)2(μ-Spy)(μ-PPh2py)](NO3)