[2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

Base Information

Chemical Name:[2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate
CAS No.:865308-31-2
Molecular Formula:C₂₁H₃₄O₅Si
Molecular Weight:394.583
Hs Code.:

Synonyms:[2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

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Chemical Property of [2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

Chemical Property:

Purity/Quality:

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Technology Process of [2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

There total 7 articles about [2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 886588-97-2
(2R,4E)-2-(2-[t-butyldimethylsiloxy]ethyl)-3-(cumyldimethylsiloxy)-2-hydroxyhex-4-enyl acetate

: 865308-22-1
[2-(1R,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

: 865308-31-2
[2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; at 20 ℃;
DOI:10.1039/b507401k

Reference yield:

: 1027938-82-4
cumyldimethylsilyl trifluoromethanesulfonate

: 865308-31-2
[2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

Guidance literature:: Multi-step reaction with 5 steps

1: 83 percent / pyridine / 0 °C

2: 92 percent / DIBAL / CH₂Cl₂ / -18 °C

3: 45 percent / lithium di-tert-butylbiphenylide / tetrahydrofuran / -78 °C

4: 98 percent / pyridine; DMAP / 20 °C

5: aq. HCl / tetrahydrofuran / 20 °C

With pyridine; hydrogenchloride; dmap; lithium di-tert-butylbiphenylide; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1039/b507401k

Reference yield:

: methyl (4E)-2-benzyloxy-2-(2-[t-butyldimethylsiloxy]ethyl)-3-hydroxyhex-4-enoate

: 865308-31-2
[2-(1S,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate

Guidance literature:: Multi-step reaction with 5 steps

1: 83 percent / pyridine / 0 °C

2: 92 percent / DIBAL / CH₂Cl₂ / -18 °C

3: 45 percent / lithium di-tert-butylbiphenylide / tetrahydrofuran / -78 °C

4: 98 percent / pyridine; DMAP / 20 °C

5: aq. HCl / tetrahydrofuran / 20 °C

With pyridine; hydrogenchloride; dmap; lithium di-tert-butylbiphenylide; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1039/b507401k