K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)

Base Information

Chemical Name:K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)
CAS No.:53897-03-3
Molecular Formula:C₂₅H₂₀FeN₂P*K
Molecular Weight:474.366
Hs Code.:

Synonyms:K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)

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Chemical Property of K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)

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Technology Process of K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)

There total 1 articles about K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: potassium cyclopentadienylcarbonyldicyanoferrate(II)

: 603-35-0
triphenylphosphine

: 53897-03-3
K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)

Guidance literature:: In methanol; acetonitrile; 1:1 mixture of acetonitrile/methanol added to KCpFe(CN)2(CO) and PPh3 ina photolysis vessel, an argon purge bubbled through the reaction slurry and the mixture photolyzed for 2 h while monitoring the IR spectra in t he ν(CO) region; product precipitated, solvent removed under vacuum, product dissolved in1-propanol, filtered through a frit containing Celite, solvent removed under vacuum, solid washed with pentane;
DOI:10.1002/ejic.200300304

Reference yield: 83.0%

: 53897-03-3
K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)

: 637764-83-1
H[CpFe(PPh₃)(CN)2]

Guidance literature:: With HCl; In methanol; (Ar); concd. HCl added to Fe complex in MeOH while stirring at room temp., reacted for 1 h; pptd. (H2O), decanted, washed (H2O, then MeOH), dried (vac.); elem. anal.;
DOI:10.1021/ic0347900

Reference yield: 74.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 53897-03-3
K(cyclopentadienyl)iron(cyanide)2(triphenylphosphane)

: 10139-47-6
zinc(II) iodide

: [CpFe(PPh3)(μ-CN)2ZnI(THF)]2

Guidance literature:: In acetonitrile; byproducts: KI; (Ar); ZnI2 in MeCN added slowly to Fe complex in MeCN, stirred for 1 h, evapd. (vac.), dissolved in THF; filtered, evapd. (vac.); elem. anal.;
DOI:10.1021/ic0347900