C₂₈H₃₅NO₇Si

Base Information

Chemical Name:C₂₈H₃₅NO₇Si
CAS No.:200182-34-9
Molecular Formula:C₂₈H₃₅NO₇Si
Molecular Weight:525.674
Hs Code.:

C<sub>28</sub>H<sub>35</sub>NO<sub>7</sub>Si

Synonyms:C₂₈H₃₅NO₇Si

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Chemical Property of C₂₈H₃₅NO₇Si

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Technology Process of C₂₈H₃₅NO₇Si

There total 19 articles about C₂₈H₃₅NO₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 200182-33-8
4-Hydroxy-benzo[1,3]dioxole-5-carboxylic acid [(1R,5S,6R)-5-(tert-butyl-dimethyl-silanyloxy)-7-oxa-bicyclo[4.1.0]hept-3-en-3-yl]-(4-methoxy-benzyl)-amide

: 200182-34-9
C₂₈H₃₅NO₇Si

Guidance literature:: In benzene; Irradiation;
DOI:10.1021/ja972950z

Reference yield:

: 54162-19-5
2,4-Cyclohexadien-1-carbonsaeure-methylester

: 200182-34-9
C₂₈H₃₅NO₇Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: O₂; Rose Bengal / acetone / 8 h / -10 °C / Irradiation

1.2: RuCl₂(PPh₃)3 / CH₂Cl₂ / -10 - 20 °C

1.3: 42 percent / NaOMe / methanol / 0.5 h / -5 °C

2.1: 99 percent / Et₃N; 4-dimethylaminopyridine / CH₂Cl₂ / 0 - 20 °C

3.1: 80 percent Turnov_. / cholesterol esterase; aq. NaOH / 36 h / 5 °C / pH 7.7

4.1: 98 percent / imidazole / dimethylformamide / 0.67 h / 20 °C

5.1: 81 percent Turnov_. / LiOH*H₂O / methanol / 48 h / -5 °C

6.1: diphenylphosphorazidate; Et₃N / benzene / 1 h

6.2: toluene / 1 h / 110 °C

7.1: n-BuLi / tetrahydrofuran; pentane / 0.5 h / -100 °C

7.2: tetrahydrofuran; toluene; pentane / 0.75 h / -100 °C

8.1: NaH / dimethylformamide / 0.5 h / -5 °C

8.2: dimethylformamide / 0.25 h / -5 °C

9.1: 76 percent / pyridinium p-toluenesulfonate / methanol / 2 h / 20 °C

10.1: 30 percent / benzene / 48 h / 5 °C / UV-irradiation

With 1H-imidazole; dmap; lithium hydroxide; sodium hydroxide; n-butyllithium; cholesterol esterase; diphenyl phosphoryl azide; oxygen; pyridinium p-toluenesulfonate; rose bengal; sodium hydride; triethylamine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; acetone; pentane; benzene; 1.1: Oxidation / 1.2: Epoxidation / 1.3: Ring cleavage / 2.1: Acylation / 3.1: Hydrolysis / 4.1: silylation / 5.1: Hydrolysis / 6.1: azidation / 6.2: Rearrangement / 7.1: Metallation / 7.2: Addition / 8.1: Metallation / 8.2: Substitution / 9.1: deprotection / 10.1: Cyclization;
DOI:10.1021/ja000930i

Reference yield:

: 200182-30-5
methyl 2-hydroxy-7-oxabicyclo[4.1.0]hept-3-ene-4-carboxylate

: 200182-34-9
C₂₈H₃₅NO₇Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: 99 percent / Et₃N; 4-dimethylaminopyridine / CH₂Cl₂ / 0 - 20 °C

2.1: 80 percent Turnov_. / cholesterol esterase; aq. NaOH / 36 h / 5 °C / pH 7.7

3.1: 98 percent / imidazole / dimethylformamide / 0.67 h / 20 °C

4.1: 81 percent Turnov_. / LiOH*H₂O / methanol / 48 h / -5 °C

5.1: diphenylphosphorazidate; Et₃N / benzene / 1 h

5.2: toluene / 1 h / 110 °C

6.1: n-BuLi / tetrahydrofuran; pentane / 0.5 h / -100 °C

6.2: tetrahydrofuran; toluene; pentane / 0.75 h / -100 °C

7.1: NaH / dimethylformamide / 0.5 h / -5 °C

7.2: dimethylformamide / 0.25 h / -5 °C

8.1: 76 percent / pyridinium p-toluenesulfonate / methanol / 2 h / 20 °C

9.1: 30 percent / benzene / 48 h / 5 °C / UV-irradiation

With 1H-imidazole; dmap; lithium hydroxide; sodium hydroxide; n-butyllithium; cholesterol esterase; diphenyl phosphoryl azide; pyridinium p-toluenesulfonate; sodium hydride; triethylamine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; pentane; benzene; 1.1: Acylation / 2.1: Hydrolysis / 3.1: silylation / 4.1: Hydrolysis / 5.1: azidation / 5.2: Rearrangement / 6.1: Metallation / 6.2: Addition / 7.1: Metallation / 7.2: Substitution / 8.1: deprotection / 9.1: Cyclization;
DOI:10.1021/ja000930i