([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane

Base Information

• Chemical Name: ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane
• CAS No.: 430430-71-0
• Molecular Formula: C₁₉H₁₆S
• Molecular Weight: 276.402
• Mol file: 430430-71-0.mol

Synonyms:([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane

Chemical Property of ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane

There total 11 articles about ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

thiophenol (108-98-5) + [1,1'-biphenyl]-4-ylmethyl methanesulfonate (376640-26-5) → ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane (430430-71-0)

Guidance literature:

With potassium hydroxide; In ethanol; for 1h; Ambient temperature;

DOI:10.1016/S0040-4020(97)00351-7

Reference yield: 89.0%

biphenyl-4-yl methanol (3597-91-9) + thiophenol (108-98-5) → ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane (430430-71-0)

Guidance literature:

With nanolayered cobalt-molybdenum sulphide with Co/(Mo+Co) mole ratio 0.83; In Hexadecane; toluene; at 180 ℃; for 18h; under 2625.26 Torr; chemoselective reaction; Inert atmosphere; Autoclave;

DOI:10.1039/c8sc05782f

Reference yield: 88.0%

4-(fluoromethyl)-1,1’-biphenyl + thiophenol (108-98-5) → ([1,1'-biphenyl]-4-ylmethyl)(phenyl)sulfane (430430-71-0)

Guidance literature:

With water; 1,8-diazabicyclo[5.4.0]undec-7-ene; In isopropyl alcohol; at 70 ℃; for 18h;

DOI:10.1021/ol400765a

upstream raw materials:

thiophenol

[1,1'-biphenyl]-4-ylmethyl methanesulfonate

4-(phenoxymethyl)-1,1'-biphenyl

sodium thiophenolate

Downstream raw materials:

4-benzenesulfinylmethylbiphenyl

4-((phenylsulfonyl)methyl)-1,1′-biphenyl