[(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

Base Information

• Chemical Name: [(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]
• CAS No.: 431882-02-9
• Molecular Formula: C₃₂H₁₂BF₂₄*C₃₂H₄₁Cl₂PRhSi
• Molecular Weight: 1521.77

Synonyms:[(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

Chemical Property of [(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

Chemical Property:

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Technology Process of [(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

There total 1 articles about [(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[(C5(CH3)5)(P(CH3)3)Rh(CH3)(dichloromethane)][B(3,5-C6H3(CF3)2)4] (431882-00-7) + HSiPh3 (789-25-3) → [(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(dichloromethane)][B(3,5-C6H3(CF3)2)4] (431882-02-9)

Guidance literature:

In dichloromethane; byproducts: CH4; the react. was complete within a few s at 25°C;

DOI:10.1021/ja0255094

Reference yield:

tert-butyl isocyanide (630-18-2) + [(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(dichloromethane)][B(3,5-C6H3(CF3)2)4] (431882-02-9) → [(C5(CH3)5)(P(CH3)3)Rh(C(CH3)3)(CNSi(C6H5)3)][B(3,5-C6H3(CF3)2)4] (431882-29-0)

Guidance literature:

In further solvent(s); (inert atm.); heating a soln. of rhodium complex and nitrile in C6D5Cl at 50°C; not isolated, detected by NMR; Kinetics;

DOI:10.1021/ja034468o

Reference yield:

[(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(dichloromethane)][B(3,5-C6H3(CF3)2)4] (431882-02-9) + 4-CF3C6H4CN (455-18-5) → [(C5(CH3)5)(P(CH3)3)Rh((4-trifluoromethyl)C6H4)(CNSi(C6H5)3)][B(3,5-C6H3(CF3)2)4] (431882-17-6)

Guidance literature:

In dichloromethane-d2; (inert atm.); addn. of a soln. of nitrile in CD2Cl2 to a soln. of rhodium complex in CD2Cl2 in an NMR tube at -78°C, warming to 0°C; not isolated, detected by NMR; Kinetics;

DOI:10.1021/ja034468o

upstream raw materials:

[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

HSiPh₃

Downstream raw materials:

[(C₅(CH₃)5)(P(CH₃)3)Rh((4-trifluoromethyl)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

[(C₅(CH₃)5)(P(CH₃)3)Rh(CH(CH₃)2)(CNSi(C₆H₅)3)]B(3,5-C₆H₃(CF₃)2)4

[(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(η1-NCC(CH3)3)][B(3,5-C6H3(CF3)2)4]

[(C₅(CH₃)5)(P(CH₃)3)Rh(C(CH₃)3)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

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