4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside

Base Information

• Chemical Name: 4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside
• CAS No.: 164665-76-3
• Molecular Formula: C₂₀H₂₈O₇
• Molecular Weight: 380.438
• Mol file: 164665-76-3.mol

Synonyms:4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside

Chemical Property of 4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside

There total 2 articles about 4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2,3,5,6-di-O-isopropylidene-D-mannofuranose (7757-38-2,14131-84-1,23262-78-4,27108-13-0,33823-04-0,34685-42-2,57819-52-0,78039-08-4,78039-12-0,78964-16-6,94842-76-9,149342-31-4) + p-methoxybenzyl chloride (824-94-2) → 4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside (164665-76-3)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; for 24h; Ambient temperature;

DOI:10.1021/jo971323p

Reference yield: 78.0%

p-methoxybenzyl chloride (824-94-2) + 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose (14131-84-1) → 4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside (164665-76-3)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide;

DOI:10.1016/j.carres.2017.08.011

Reference yield: 96.0%

4-methoxybenzyl 2,3,5,6-di-O-isopropylidene-α-D-mannofuranoside (164665-76-3) → 2,3-O-isopropylidene-1-O-p-methoxybenzyl-α-D-mannofuranoside (164665-83-2)

Guidance literature:

With acetic acid; In water;

DOI:10.1016/j.carres.2017.08.011

upstream raw materials:

2,3,5,6-di-O-isopropylidene-D-mannofuranose

p-methoxybenzyl chloride

2,3:5,6-di-O-isopropylidene-α-D-mannofuranose

Downstream raw materials:

2,3-O-isopropylidene-1-O-p-methoxybenzyl-α-D-mannofuranoside

5-O-benzyl-2,3-O-isopropylidene-α-D-mannofuranuronic acid

4-methoxybenzyl 5-O-methyl-2,3-O-isopropylidene-α-D-mannofuranoside

p-methoxybenzyl 2,3-O-isopropylidene-5-O-methyl-α-D-mannofuranosiduronic acid