C₃₆H₅₀O₆Si

Base Information

Chemical Name:C₃₆H₅₀O₆Si
CAS No.:1261148-40-6
Molecular Formula:C₃₆H₅₀O₆Si
Molecular Weight:606.875
Hs Code.:

C<sub>36</sub>H<sub>50</sub>O<sub>6</sub>Si

Synonyms:C₃₆H₅₀O₆Si

Suppliers and Price of C₃₆H₅₀O₆Si

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₃₆H₅₀O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₃₆H₅₀O₆Si

There total 28 articles about C₃₆H₅₀O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1261148-48-4
C₃₆H₅₀O₆Si

: 1261148-40-6
C₃₆H₅₀O₆Si

Guidance literature:: With camphor-10-sulfonic acid; In dichloromethane; at 0 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ja109531d

Reference yield:

: 1227265-23-7
C₃₁H₃₆O₄Si

: 1261148-40-6
C₃₆H₅₀O₆Si

Guidance literature:: Multi-step reaction with 28 steps

1.1: diethyl ether / 1 h / -78 °C / Inert atmosphere

2.1: 20 % Pd(OH)2/C; hydrogen / ethanol; ethyl acetate / 18 h / 25 °C

3.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane / 18 h / 25 °C / Inert atmosphere

4.1: dichloromethane / 4 h / 25 °C / Inert atmosphere

5.1: 2,6-dimethylpyridine / dichloromethane / 2 h / 0 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / dichloromethane / -78 - 0 °C / Inert atmosphere

7.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 0.33 h / -20 °C / Molecular sieve; Inert atmosphere

7.2: 1 h / -20 °C / Inert atmosphere

8.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 9 h / 0 - 25 °C / Inert atmosphere

9.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

9.2: 1 h / -78 - 0 °C / Inert atmosphere

10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

11.1: camphor-10-sulfonic acid / dichloromethane / 0.5 h / 25 °C / Inert atmosphere

12.1: 1H-imidazole / dichloromethane / 0 - 25 °C / Inert atmosphere

13.1: borane-THF / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

13.2: 1 h / 0 °C

14.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 1 h / 0 - 25 °C / Molecular sieve; Inert atmosphere

15.1: tetrahydrofuran; diethyl ether / 1 h / 0 °C / Inert atmosphere

16.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 12 h / 0 - 25 °C / Molecular sieve; Inert atmosphere

17.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

18.1: 4-methyl-morpholine / dichloromethane / 23 h / 25 °C / Inert atmosphere

19.1: methanol; samarium diiodide / tetrahydrofuran / 0.33 h / 0 °C / Inert atmosphere

20.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

21.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

22.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

22.2: 1 h / 0 °C / Inert atmosphere

23.1: diisobutylaluminium hydride / dichloromethane / 0.67 h / -78 °C / Inert atmosphere

24.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 0.5 h / -20 °C / Molecular sieve; Inert atmosphere

24.2: 1 h / -20 °C / Inert atmosphere

25.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 1 h / 25 °C / Inert atmosphere

26.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

26.2: -78 - 0 °C / Inert atmosphere

27.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

28.1: camphor-10-sulfonic acid / dichloromethane / 3 h / 0 °C / Inert atmosphere

With 4-methyl-morpholine; 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; methanol; samarium diiodide; tetrapropylammonium perruthennate; borane-THF; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; diethyl (2S,3S)-tartrate; [bis(acetoxy)iodo]benzene; 20 % Pd(OH)2/C; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; hydrogen; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; dimethyl sulfoxide; ethyl acetate; toluene; 1.1: Grignard reaction / 7.1: Sharpless epoxidation / 7.2: Sharpless epoxidation / 9.1: Whiting reaction / 9.2: Whiting reaction / 22.1: Horner-Wadsworth-Emmons olefination / 22.2: Horner-Wadsworth-Emmons olefination / 24.1: Sharpless epoxidation / 24.2: Sharpless epoxidation;
DOI:10.1021/ja109531d

Reference yield:

: C₃₃H₅₀O₅Si₂

: 1261148-40-6
C₃₆H₅₀O₆Si

Guidance literature:: Multi-step reaction with 23 steps

1.1: diisobutylaluminium hydride / dichloromethane / -78 - 0 °C / Inert atmosphere

2.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 0.33 h / -20 °C / Molecular sieve; Inert atmosphere

2.2: 1 h / -20 °C / Inert atmosphere

3.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 9 h / 0 - 25 °C / Inert atmosphere

4.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

4.2: 1 h / -78 - 0 °C / Inert atmosphere

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

6.1: camphor-10-sulfonic acid / dichloromethane / 0.5 h / 25 °C / Inert atmosphere

7.1: 1H-imidazole / dichloromethane / 0 - 25 °C / Inert atmosphere

8.1: borane-THF / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

8.2: 1 h / 0 °C

9.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 1 h / 0 - 25 °C / Molecular sieve; Inert atmosphere

10.1: tetrahydrofuran; diethyl ether / 1 h / 0 °C / Inert atmosphere

11.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 12 h / 0 - 25 °C / Molecular sieve; Inert atmosphere

12.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

13.1: 4-methyl-morpholine / dichloromethane / 23 h / 25 °C / Inert atmosphere

14.1: methanol; samarium diiodide / tetrahydrofuran / 0.33 h / 0 °C / Inert atmosphere

15.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

16.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

17.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

17.2: 1 h / 0 °C / Inert atmosphere

18.1: diisobutylaluminium hydride / dichloromethane / 0.67 h / -78 °C / Inert atmosphere

19.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 0.5 h / -20 °C / Molecular sieve; Inert atmosphere

19.2: 1 h / -20 °C / Inert atmosphere

20.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 1 h / 25 °C / Inert atmosphere

21.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

21.2: -78 - 0 °C / Inert atmosphere

22.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

23.1: camphor-10-sulfonic acid / dichloromethane / 3 h / 0 °C / Inert atmosphere

With 4-methyl-morpholine; 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; methanol; samarium diiodide; tetrapropylammonium perruthennate; borane-THF; diethyl (2S,3S)-tartrate; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane; dimethyl sulfoxide; toluene; 2.1: Sharpless epoxidation / 2.2: Sharpless epoxidation / 4.1: Whiting reaction / 4.2: Whiting reaction / 17.1: Horner-Wadsworth-Emmons olefination / 17.2: Horner-Wadsworth-Emmons olefination / 19.1: Sharpless epoxidation / 19.2: Sharpless epoxidation;
DOI:10.1021/ja109531d