(1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate

Base Information

Chemical Name:(1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate
CAS No.:1269141-76-5
Molecular Formula:CF₃O₃S*C₁₇H₂₄BrS
Molecular Weight:489.418
Hs Code.:

Synonyms:(1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate

Chemical Property:

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Technology Process of (1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate

There total 1 articles about (1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 1208985-45-8
(1S,4S,5S)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane

: 33454-82-9
lithium trifluoromethanesulfonate

: 3433-80-5
1-Bromo-2-bromomethyl-benzene

: 1269141-76-5
(1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate

Guidance literature:: In dichloromethane; water; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ol200263g

Reference yield:

: 1075183-18-4
N-(cyclohex-1-en-1-ylmethylene)-4-methylbenzenesulfonamide

: 1269141-76-5
(1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate

: 1269141-91-4
(2S,3S)-2-(2-bromophenyl)-3-(cyclohex-1-en-1-yl)-1-tosylaziridine

: C₂₁H₂₂BrNO₂S

Guidance literature:: With potassium carbonate; In acetonitrile; at 0 - 20 ℃; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol200263g

Reference yield:

: 1075183-18-4
N-(cyclohex-1-en-1-ylmethylene)-4-methylbenzenesulfonamide

: 1269141-76-5
(1S,4S,5S,6S)-6-(4-bromobenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate

: 1269142-02-0
(2R,7aR)-2-(2-bromophenyl)-1-tosyl-2,4,5,6,7,7a-hexahydro-1H-indole

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / acetonitrile / 0 - 20 °C / Inert atmosphere

2: bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) monohydrate / toluene / 2 h / 150 °C / Inert atmosphere

With bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) monohydrate; potassium carbonate; In toluene; acetonitrile;
DOI:10.1021/ol200263g