{(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

Base Information

Chemical Name:{(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4
CAS No.:123581-52-2
Molecular Formula:C₅₉H₅₆I₂N₃OP₄Rh₂*ClO₄
Molecular Weight:1506.08
Hs Code.:

Synonyms:{(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

Suppliers and Price of {(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

There total 5 articles about {(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: {(OC)IRh(μ-pyrazolate)(μ-CO)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

: 123581-52-2
{(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

Guidance literature:: With N₂; In chloroform; bubbling N2 through refluxing soln. of Rh-complex in CHCl3 (atm. pressure); partial concn. (reduced pressure), slow addn. of Et2O, filtration, washing (Et2O), air-drying; elem. anal.;

Reference yield:

: 123581-59-9
{(OC)Rh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2Rh(CN-t-Bu)}ClO4

: 123581-52-2
{(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

Guidance literature:: With iodine; In dichloromethane; addn. of I2 in CH2Cl2 to Rh-complex in CH2Cl2, stirring (15 min); partial concn. (reduced pressure), pptn. on slow addn. of Et2O, filtration, washing (Et2O), air-drying;

Reference yield:

: 98767-13-6
{Rh2(μ-pyrazolate)I2(CO)2(μ-bis(diphenylphosphino)methane)2}ClO4

: 123581-52-2
{(OC)IRh(μ-pyrazolate)(μ-bis(diphenylphosphino)methane)2RhI(CN-t-Bu)}ClO4

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane

2: N₂ / chloroform

With N₂; In dichloromethane; chloroform;