1-(2-methylphenyl)-o-carbaborane

Base Information

Chemical Name:1-(2-methylphenyl)-o-carbaborane
CAS No.:111447-49-5
Molecular Formula:C₉H₁₈B₁₀
Molecular Weight:234.352
Hs Code.:

Synonyms:1-(2-methylphenyl)-o-carbaborane

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Chemical Property of 1-(2-methylphenyl)-o-carbaborane

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Technology Process of 1-(2-methylphenyl)-o-carbaborane

There total 3 articles about 1-(2-methylphenyl)-o-carbaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 16872-09-6
1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 615-37-2
ortho-methylphenyl iodide

: 111447-49-5
1-(2-methylphenyl)-o-carbaborane

Guidance literature:: 1,2-dicarba-closo-dodecaborane⁽¹²⁾; With isopropylmagnesium chloride; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;

ortho-methylphenyl iodide; With nickel dichloride; In toluene; at 140 ℃; for 12h; Inert atmosphere;
DOI:10.1002/anie.201502502

Reference yield: 50.0%

: 16872-09-6
1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 2093-46-1
2-methylphenyl diazonium tetrafluoroborate

: 111447-49-5
1-(2-methylphenyl)-o-carbaborane

Guidance literature:: With n-butyllithium; copper(l) chloride; In tetrahydrofuran; diethyl ether; hexane; under N2; dropwise addn. of BuLi in hexane to a soln. of o-carborane inether at 0-5°C with stirring; addn. of anhydr. CuCl with stirring; addn. of THF; heating at 40°C for 10 min; cooling to 0-5°C; addn. of BF4-salt.; addn. of MeOH at 20°C; filtration of ppt. and washing (benzene, ether); washing of filtrates (aq. HCl, H2O) and drying over CaCl2 or Na2SO4; evapn. in vac.; TLC (Siloful, benzene-petroleum ether); recrystn. (MeOH); elem. anal.;

Reference yield:

: decaborane

: 766-47-2
1-ethynyl-2-methylbenzene

: 111447-49-5
1-(2-methylphenyl)-o-carbaborane

Guidance literature:: With 1-butyl-3-methylimidazolium chloride; In toluene; for 0.5h; Inert atmosphere; Schlenk technique; Reflux;
DOI:10.1016/j.tetlet.2020.152625