Benzyl 4-oxoazetidine-2-carboxylate

Base Information

Chemical Name:Benzyl 4-oxoazetidine-2-carboxylate
CAS No.:87791-58-0
Molecular Formula:C11H11 N O3
Molecular Weight:205.213
Hs Code.:2933790090
European Community (EC) Number:675-999-5
DSSTox Substance ID:DTXSID40384578
Nikkaji Number:J1.469.050F
Mol file:87791-58-0.mol

Synonyms:benzyl 4-oxoazetidine-2-carboxylate;87791-58-0;Benzyl 4-Oxo-2-azetidinecarboxylate;4-(benzyloxycarbonyl)-2-azetidinone;2-azetidinecarboxylic acid, 4-oxo-, phenylmethyl ester;MFCD00661973;MFCD00798164;Benzyl4-oxoazetidine-2-carboxylate;BENZYL (S)-4-OXOAZETIDINE-2-CARBOXYLATE;Maybridge3_001414;Oprea1_260819;2-Azetidinecarboxylic acid, 4-oxo-, phenylmethyl ester, (R)-;(S)-4-Cbz-azetidin-2-one;SCHEMBL4695211;AMY4409;DTXSID40384578;WGLLBHSIXLWVFU-UHFFFAOYSA-N;HMS1435A06;4-benzyloxycarbonyl azetidin-2-one;Bis(1-methylpropyl)carbamicchloride;CCG-45920;AKOS015855328;AC-9161;DS-4811;MB01372;SB22125;IDI1_012801;benzyl (R)-4-oxoazetidine-2-carboxylate;SY096980;CS-0149861;FT-0653364;FT-0693088;4-Oxoazetidine-2-carboxylic acid benzyl ester;4-oxo-azetidine-2-carboxylic acid benzyl ester;A13062;Benzyl (S)-(?)-4-oxo-2-azetidinecarboxylate;SR-01000635657-1

Suppliers and Price of Benzyl 4-oxoazetidine-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
benzyl4-oxoazetidine-2-carboxylate
500mg
$ 310.00

Crysdot
Benzyl4-oxoazetidine-2-carboxylate 97%
1g
$ 150.00

Crysdot
Benzyl4-oxoazetidine-2-carboxylate 97%
250mg
$ 60.00

BLDpharm
Benzyl4-oxoazetidine-2-carboxylate 97%
250mg
$ 72.00

BLDpharm
Benzyl4-oxoazetidine-2-carboxylate 97%
100mg
$ 44.00

BLDpharm
Benzyl4-oxoazetidine-2-carboxylate 97%
1g
$ 148.00

American Custom Chemicals Corporation
4-(BENZYLOXYCARBONYL)-2-AZETIDINONE 95.00%
1G
$ 685.21

Ambeed
Benzyl4-oxoazetidine-2-carboxylate 97%
1g
$ 141.00

Ambeed
Benzyl4-oxoazetidine-2-carboxylate 97%
250mg
$ 74.00

Ambeed
Benzyl4-oxoazetidine-2-carboxylate 97%
100mg
$ 44.00

Total 29 raw suppliers

Chemical Property of Benzyl 4-oxoazetidine-2-carboxylate

Chemical Property:

Vapor Pressure:9.28E-07mmHg at 25°C
Boiling Point:404.7ºC at 760 mmHg
PKA:13.75±0.40(Predicted)
Flash Point:198.5ºC
PSA：55.40000
Density:1.268g/cm3
LogP:0.94710
Storage Temp.:2-8°C
XLogP3:0.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:205.07389321
Heavy Atom Count:15
Complexity:259

Purity/Quality:

99%, ^*data from raw suppliers

benzyl4-oxoazetidine-2-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(NC1=O)C(=O)OCC2=CC=CC=C2

Technology Process of Benzyl 4-oxoazetidine-2-carboxylate

There total 2 articles about Benzyl 4-oxoazetidine-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 4079-61-2
2-amino-succinic acid dibenzyl ester

: 87791-58-0
azetidinone-4-carboxylic acid benzyl ester

Guidance literature:: 2-amino-succinic acid dibenzyl ester; With chloro-trimethyl-silane; triethylamine; In diethyl ether; at 0 ℃; for 2h; Inert atmosphere;

In diethyl ether; at 0 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ja507576a

Reference yield:

: 87791-58-0
azetidinone-4-carboxylic acid benzyl ester

Guidance literature:: BZL, TSi-Asp-OBZL, EtMgBr;

Reference yield: 100.0%

: 87791-58-0
azetidinone-4-carboxylic acid benzyl ester

: 1-chloro-4-oxo-azetidine-2-carboxylic acid benzyl ester

Guidance literature:: With sodium hypochlorite; acetic acid; tert-butyl alcohol; In Isopropyl acetate; at 0 ℃; for 1h;
DOI:10.1016/j.tetlet.2004.12.088