tetraphenylarsonium cis-dihydrotetracarbonylmanganate

Base Information

• Chemical Name: tetraphenylarsonium cis-dihydrotetracarbonylmanganate
• CAS No.: 118831-26-8
• Molecular Formula: C₄H₂MnO₄*C₂₄H₂₀As
• Molecular Weight: 552.34
• Mol file: 118831-26-8.mol

Synonyms:tetraphenylarsonium cis-dihydrotetracarbonylmanganate

Chemical Property of tetraphenylarsonium cis-dihydrotetracarbonylmanganate

Chemical Property:

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Technology Process of tetraphenylarsonium cis-dihydrotetracarbonylmanganate

There total 1 articles about tetraphenylarsonium cis-dihydrotetracarbonylmanganate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

trisodium tetracarbonylmanganate(3-) (59123-04-5) + tetraphenylarsonium chloride (507-28-8,14842-08-1) → tetraphenylarsonium cis-dihydrotetracarbonylmanganate (118831-26-8)

Guidance literature:

With ethanol; In N,N,N,N,N,N-hexamethylphosphoric triamide; water; inert atm., stoich. amount of ethanol added slowly to Mn-complex in HMTP, then Ph4AsCl in H2O (0°C) added in excess; collection of ppt. (filtration), washing (cold water), drying (vac., 12h); elem. anal.;

DOI:10.1021/ja00188a029

upstream raw materials:

trisodium tetracarbonylmanganate^(3-)

tetraphenylarsonium chloride