5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione

Base Information

Chemical Name:5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione
CAS No.:1453207-08-3
Molecular Formula:C₂₆H₃₆O₇
Molecular Weight:460.568
Hs Code.:

Synonyms:5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione

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Chemical Property of 5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione

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Technology Process of 5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione

There total 15 articles about 5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 26103-97-9
phloroisovalerophenone

: 2,2,4,4-tetramethyl-6-(3-methylbutylidene) cyclohexane-1,3,5-trione

: 1453207-08-3
5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione

Guidance literature:: With nickel(II) perchlorate hexahydrate; In dichloromethane; acetic acid; at 20 - 40 ℃; for 17h; Reagent/catalyst; Inert atmosphere; Molecular sieve;
DOI:10.1021/acs.joc.5b01570

Reference yield: 80.0%

: 26103-97-9
phloroisovalerophenone

: 2,2,4,4-tetramethyl-6-(3-methylbutylidene) cyclohexane-1,3,5-trione

: 1453207-08-3
5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione

: 8α-hydroxy-3-isopropyl-6,6,8,8-tetramethyl-8,8-dihydrobenzo[c][1,2]dioxine-5,7(3H,6H)-dione

Guidance literature:: With nickel(II) perchlorate hexahydrate; In dichloromethane; acetic acid; at 20 - 40 ℃; for 17h; Reagent/catalyst; Inert atmosphere; Molecular sieve;
DOI:10.1021/acs.joc.5b01570

Reference yield:

: 26103-97-9
phloroisovalerophenone

: 2,2,4,4-tetramethyl-6-(3-methylbutylidene) cyclohexane-1,3,5-trione

: 1453207-08-3
5-hydroxy-2,2,6,6-tetramethyl-4-(3-methyl-1-(2,4,6-trihydroxy-3-(3-methylbutanoyl)phenyl)butyl)-cyclohex-4-ene-1,3-dione

: C₂₆H₃₈O₇

Guidance literature:: phloroisovalerophenone; With sodium hydride; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

2,2,4,4-tetramethyl-6-(3-methylbutylidene) cyclohexane-1,3,5-trione; In tetrahydrofuran; at 20 ℃; for 1.33333h; Overall yield = 42 %; Overall yield = 5.6 g; Inert atmosphere;
DOI:10.1016/j.tet.2013.07.091