METHYLTRIALLYLSILANE

Base Information

• Chemical Name: METHYLTRIALLYLSILANE
• CAS No.: 1112-91-0
• Molecular Formula: C10H18 Si
• Molecular Weight: 166.34
• Hs Code.: 29310099
• Mol file: 1112-91-0.mol

Synonyms:Silane,methyltri-2-propenyl- (9CI); Silane, triallylmethyl- (6CI,7CI,8CI);Triallylmethylsilane

Chemical Property of METHYLTRIALLYLSILANE

Chemical Property:

• Vapor Pressure: 1.88mmHg at 25°C
• Refractive Index: 1.4661-1.4681
• Boiling Point: 171.2°C at 760 mmHg
• Flash Point: 45.7°C
• PSA: 0.00000
• Density: 0.775g/cm³
• LogP: 3.62300
• Storage Temp.: Flammables area

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triallyl(methyl)silane >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38-10
• Safety Statements: 37/39-26-16

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYLTRIALLYLSILANE

There total 8 articles about METHYLTRIALLYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

Methyltrichlorosilane (75-79-6) + allylsamarium bromide (346713-20-0) → methyltriallylsilane (1112-91-0)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1.5h;

DOI:10.1016/j.jorganchem.2006.07.023

Reference yield: 79.0%

allyldichloromethylsilane (1873-92-3) + allyl bromide (106-95-6) → methyltriallylsilane (1112-91-0)

Guidance literature:

With zinc; In tetrahydrofuran; for 0.166667h; Inert atmosphere; Sonication;

DOI:10.1039/c4ob00294f

Reference yield: 78.1%

Methyltrichlorosilane (75-79-6) + allylmagnesium bromide (2622-05-1) → methyltriallylsilane (1112-91-0)

Guidance literature:

With 3-chloroprop-1-ene; In diethyl ether; for 3h; Heating;

upstream raw materials:

Methyltrichlorosilane

allylmagnesium bromide

allyl bromide

allylmagnesium bromide

Refernces

• 1、 Li, Zhifang,Cao, Xiaojun,Lai, Guoqiao,Liu, Jinhua,Ni, Yong,Wu, Jirong,Qiu, Huayu. "Controlled introduction of allylic group to chlorosilanes". . p. 4740 - 4746. Retrieved 2007/10/03.
• 2、 Boudin, Alain,Cerveau, Genevieve,Chuit, Claude,Corriu, Robert J. P.. "Reactivity of Hypervalent Species: Reactions of Anionic Penta-Coordinated Silicon Complexes towards Nucleophiles". . p. 101 - 106. Retrieved 2007/10/02.