4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol

Base Information

Chemical Name:4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol
CAS No.:333754-77-1
Molecular Formula:C₅₄H₅₂O₇P₂
Molecular Weight:874.95
Hs Code.:

Synonyms:4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol

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Chemical Property of 4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol

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Technology Process of 4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol

There total 10 articles about 4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 333754-76-0
{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

: 333754-77-1
4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)01923-7

Reference yield:

: 75685-01-7
2,2'-dimethoxy-1,1'-binaphthyl

: 333754-77-1
4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol

Guidance literature:: Multi-step reaction with 10 steps

1: 80 percent / AlCl₃ / CH₂Cl₂

3: LAH / tetrahydrofuran

4: 91 percent / imidazole / dimethylformamide

5: 61 percent / BuLi / diethyl ether

6: 98 percent / NaBH₄ / methanol

7: Et₃N / CH₂Cl₂

8: LiCl / dimethylformamide

9: 100 percent / NaOtBu / tetrahydrofuran

10: 89 percent / TBAF / tetrahydrofuran

With 1H-imidazole; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; aluminium trichloride; tetrabutyl ammonium fluoride; triethylamine; lithium chloride; sodium t-butanolate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 1: Friedel-Crafts acylation;
DOI:10.1016/S0040-4039(00)01923-7

Reference yield:

: 205107-27-3
4-(2,2'-dimethoxy-[1,1']binaphthalenyl-6-yl)-4-oxo-butyric acid ethyl ester

: 333754-77-1
4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butan-1-ol

Guidance literature:: Multi-step reaction with 9 steps

2: LAH / tetrahydrofuran

3: 91 percent / imidazole / dimethylformamide

4: 61 percent / BuLi / diethyl ether

5: 98 percent / NaBH₄ / methanol

6: Et₃N / CH₂Cl₂

7: LiCl / dimethylformamide

8: 100 percent / NaOtBu / tetrahydrofuran

9: 89 percent / TBAF / tetrahydrofuran

With 1H-imidazole; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; tetrabutyl ammonium fluoride; triethylamine; lithium chloride; sodium t-butanolate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)01923-7