tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane

Base Information

Chemical Name:tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane
CAS No.:606133-02-2
Molecular Formula:C₂₉H₄₀O₃Si
Molecular Weight:464.72
Hs Code.:

Synonyms:tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane

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Chemical Property of tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane

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Technology Process of tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane

There total 1 articles about tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: (Z)-2-Methylene-7-(tetrahydro-pyran-2-yloxy)-hept-5-en-1-ol

: 606133-02-2
tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 - 20 ℃; for 4h;
DOI:10.1021/ja036263l

Reference yield: 91.0%

: 606133-02-2
tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane

: 606133-04-4
6-(tert-butyldiphenylsilanyloxymethyl)-hepta-2,6-dien-1-ol

Guidance literature:: With methanol; toluene-4-sulfonic acid; at 20 ℃; for 2h;
DOI:10.1021/ja036263l

Reference yield:

: 606133-02-2
tert-butyl-[2-methylene-7-(tetrahydropyran-2-yloxy)-hept-5-enyloxy]-diphenylsilane

: [2-(5-allyloxy-pent-3-enyl)-oxiranylmethylene]-(2-phenyl-aziridin-1-yl)-amine

Guidance literature:: Multi-step reaction with 6 steps

1.1: 91 percent / p-toluenesulfonic acid; methanol / 2 h / 20 °C

2.1: sodium hydride / tetrahydrofuran / 0 °C

2.2: tetrahydrofuran / 20 °C

3.1: 30 mg / TBAF / tetrahydrofuran

4.1: 37 percent / vanadyl acetylacetonate; tert-butyl hydroperoxide / benzene / 1 h / 40 °C

5.1: 4-methylmorpholine N-oxide; tetrapropylammonium perruthenate / CH₂Cl₂ / 0.17 h / 20 °C

6.1: 15 mg / methanol / 4 h / 20 °C

With methanol; tert.-butylhydroperoxide; tetrapropylammonium perruthennate; vanadyl acetylacetonate; tetrabutyl ammonium fluoride; sodium hydride; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; In tetrahydrofuran; methanol; dichloromethane; benzene;
DOI:10.1021/ja036263l