(5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,5,7,12⁽¹⁶⁾,13-pentaene-2,2,11,11-tetracarbonitrile

Base Information

• Chemical Name: (5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,5,7,12⁽¹⁶⁾,13-pentaene-2,2,11,11-tetracarbonitrile
• CAS No.: 69435-91-2
• Molecular Formula: C₃₂H₂₄N₄
• Molecular Weight: 464.569
• Mol file: 69435-91-2.mol

Synonyms:(5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,5,7,12⁽¹⁶⁾,13-pentaene-2,2,11,11-tetracarbonitrile

Chemical Property of (5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,5,7,12⁽¹⁶⁾,13-pentaene-2,2,11,11-tetracarbonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,5,7,12⁽¹⁶⁾,13-pentaene-2,2,11,11-tetracarbonitrile

There total 3 articles about (5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,5,7,12⁽¹⁶⁾,13-pentaene-2,2,11,11-tetracarbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

cis-1,2-dicyclopropylstilbene (65045-44-5) + 7,7',8,8'-tetracyanoquinodimethane (1518-16-7,6144-37-2) → (5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1(15),5,7,12(16),13-pentaene-2,2,11,11-tetracarbonitrile (69435-91-2)

Guidance literature:

In acetonitrile; at 85 - 90 ℃; for 336h;

DOI:10.1021/ja00413a017

Reference yield: 52.0%

trans-1,2-dicyclopropylstilbene (65045-43-4) + 7,7',8,8'-tetracyanoquinodimethane (1518-16-7,6144-37-2) → (5Z,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1(15),5,7,12(16),13-pentaene-2,2,11,11-tetracarbonitrile (69435-91-2)

Guidance literature:

In acetonitrile; at 85 - 90 ℃; for 336h;

DOI:10.1021/ja00413a017

Reference yield:

→ (5E,7E)-6,7-Diphenyl-bicyclo[10.2.2]hexadeca-1(15),5,7,12(16),13-pentaene-2,2,11,11-tetracarbonitrile (69435-91-2)

Guidance literature:

Ethylen 1b u. TCNQ;

DOI:10.1039/c39780000864

upstream raw materials:

cis-1,2-dicyclopropylstilbene

7,7',8,8'-tetracyanoquinodimethane

trans-1,2-dicyclopropylstilbene

Downstream raw materials:

5,6-diphenyl<10>paracyclophane