(E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide

Base Information

• Chemical Name: (E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide
• CAS No.: 76119-03-4
• Molecular Formula: Br*C₁₄H₂₀N
• Molecular Weight: 282.224
• Mol file: 76119-03-4.mol

Synonyms:(E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide

Chemical Property of (E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide

There total 1 articles about (E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

phenylpro-2-en-1-amonium chloride (58574-62-2) + allyl bromide (106-95-6) → (E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide (76119-03-4)

Guidance literature:

With potassium carbonate; In acetonitrile; at 70 ℃; for 10h; Inert atmosphere; Glovebox;

DOI:10.1021/jacs.5b06317

Reference yield: 70.0%

(E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide (76119-03-4) → trans-3-dimethylamino-1-phenylhexa-1,5-diene (76119-04-5)

Guidance literature:

With sodium methylate; In dimethyl sulfoxide; for 8h;

DOI:10.1039/P19800001462

Reference yield:

(E)-N-allyl-N,N-dimethyl-3-phenylprop-2-en-1-aminium bromide (76119-03-4) → 3-phenylhex-5-enal (53847-16-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 70 percent / MeONa / dimethylsulfoxide / 8 h

2: 170 °C / <3,3> rearrangement of hexa-1,5-diene derivatives

3: 10N HCl / diethyl ether

With hydrogenchloride; sodium methylate; In diethyl ether; dimethyl sulfoxide;

DOI:10.1039/P19800001462

upstream raw materials:

phenylpro-2-en-1-amonium chloride

allyl bromide

Downstream raw materials:

trans-3-dimethylamino-1-phenylhexa-1,5-diene

3-phenylhex-5-enal