Technology Process of 4-tosyloxy-2,7-diiodonaphthalene
There total 4 articles about 4-tosyloxy-2,7-diiodonaphthalene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
titanium(IV) isopropylate; lithium chloride; zinc(II) iodide;
bis(benzonitrile)palladium(II) dichloride;
In
diethylene glycol dimethyl ether;
at 155 ℃;
for 14h;
DOI:10.1021/jo001356w
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 55 percent / Na2CO3 / H2O / 15 h
2: 72 percent / SOCl2 / dimethylformamide / 2 h / Heating
3: 46 percent / ZnI2; LiCl; Ti(O-i-Pr)4 / PdCl2(PhCN)2 / bis-(2-methoxy-ethyl) ether / 14 h / 155 °C
With
titanium(IV) isopropylate; thionyl chloride; sodium carbonate; lithium chloride; zinc(II) iodide;
bis(benzonitrile)palladium(II) dichloride;
In
diethylene glycol dimethyl ether; water; N,N-dimethyl-formamide;
DOI:10.1021/jo001356w
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 55 percent / Na2CO3 / H2O / 15 h
2: 72 percent / SOCl2 / dimethylformamide / 2 h / Heating
3: 46 percent / ZnI2; LiCl; Ti(O-i-Pr)4 / PdCl2(PhCN)2 / bis-(2-methoxy-ethyl) ether / 14 h / 155 °C
With
titanium(IV) isopropylate; thionyl chloride; sodium carbonate; lithium chloride; zinc(II) iodide;
bis(benzonitrile)palladium(II) dichloride;
In
diethylene glycol dimethyl ether; water; N,N-dimethyl-formamide;
DOI:10.1021/jo001356w
