1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone

Base Information

Chemical Name:1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone
CAS No.:1354396-65-8
Molecular Formula:C₂₄H₃₆O₃Si
Molecular Weight:400.634
Hs Code.:

Synonyms:1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone

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Technology Process of 1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone

There total 1 articles about 1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1-[(2R,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)prop-2-yn-1-ol

: 1354396-65-8
1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone

Guidance literature:: With sodium acetate; pyridinium chlorochromate; In dichloromethane; Molecular sieve;
DOI:10.1021/ol203114a

Reference yield: 99.0%

: 1354396-65-8
1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone

: 1354396-76-1
(S)-1-[(2R,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)prop-2-yn-1-ol

Guidance literature:: With C₃₈H₄₀N₂O₄RuS₂; In dichloromethane; isopropyl alcohol; at 20 ℃; for 1.5h; optical yield given as %de; diastereoselective reaction;
DOI:10.1021/ol203114a

Reference yield:

: 1354396-65-8
1-[(2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)propynone

: 1354396-76-1
(S)-1-[(2R,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)prop-2-yn-1-ol

: 1354396-77-2
(R)-1-[(2R,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)prop-2-yn-1-ol

Guidance literature:: With sodium tetrahydroborate; calcium chloride; In methanol; at 0 ℃; for 0.166667h; optical yield given as %de; diastereoselective reaction;
DOI:10.1021/ol203114a