(R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate

Base Information

Chemical Name:(R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate
CAS No.:1434278-12-2
Molecular Formula:C₁₆H₁₉F₃O₇S
Molecular Weight:412.384
Hs Code.:

Synonyms:(R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate

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Chemical Property of (R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate

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Technology Process of (R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate

There total 4 articles about (R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 1434278-10-0
(R)-5-hexen-2-yl 2-Hydroxy-4,6-dimethoxybenzoate

: 1434278-12-2
(R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201201296

Reference yield:

: 17397-24-9,17397-29-4,54774-27-5,626-94-8
hex-5-en-2-ol

: 1434278-12-2
(R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydride / mineral oil; 1,4-dioxane / 1 h / Inert atmosphere

1.2: 16.25 h / Inert atmosphere

2.1: Pisa₁ from Pseudomonas sp. DSM 6611 / aq. buffer / 24 h / 30 °C / pH 8 / Inert atmosphere

2.2: 2 h / 40 °C / 3.75 Torr / Inert atmosphere

3.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 16 h / 20 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine / dichloromethane / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; di-isopropyl azodicarboxylate; Pisa₁ from Pseudomonas sp. DSM 6611; sodium hydride; triphenylphosphine; In tetrahydrofuran; 1,4-dioxane; dichloromethane; mineral oil; 3.1: |Mitsunobu Displacement;
DOI:10.1002/ejoc.201201296

Reference yield:

: 1384156-86-8
5-hexen-2-yl sulfate

: 1434278-12-2
(R)-5-hexen-2-yl 4,6-dimethoxy-2-(trifluoromethylsulfonyloxy)-benzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: Pisa₁ from Pseudomonas sp. DSM 6611 / aq. buffer / 24 h / 30 °C / pH 8 / Inert atmosphere

1.2: 2 h / 40 °C / 3.75 Torr / Inert atmosphere

2.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 16 h / 20 °C / Inert atmosphere

3.1: 2,6-dimethylpyridine / dichloromethane / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; di-isopropyl azodicarboxylate; Pisa₁ from Pseudomonas sp. DSM 6611; triphenylphosphine; In tetrahydrofuran; dichloromethane; 2.1: |Mitsunobu Displacement;
DOI:10.1002/ejoc.201201296