[5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)

Base Information

Chemical Name:[5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)
CAS No.:281211-15-2
Molecular Formula:C₆₈H₇₅IN₄Ni
Molecular Weight:1133.96
Hs Code.:

Synonyms:[5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)

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Chemical Property of [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)

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Technology Process of [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)

There total 4 articles about [5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 5-(4'-iodophenyl)-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphin

: 6018-89-9
nickel(II) acetate tetrahydrate

: 281211-15-2
[5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)

Guidance literature:: In N,N-dimethyl-formamide; refluxed for 40 min; cooled, ether added, washed (water), dried (Na2SO4), filtered,solvent removed, chromy. (silica, dichloromethane/light petroleum), solvent removed, recrystd. (CH2Cl2/CH3OH); elem. anal.;
DOI:10.1039/a910323f

Reference yield: 97.9%

: bis(acetylacetonate)nickel(II)

: 5,10,15-Tris(3,5-di-tert-butylphenyl)-20-(4-iodophenyk)porphyrin

: 281211-15-2
[5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)

Guidance literature:: In toluene; for 1.5h; Reflux;
DOI:10.1021/acs.joc.8b02907

Reference yield:

: 17610-00-3
3,5-Di-tert-butylbenzaldehyde

: 15164-44-0
p-(iodophenyl)carboxaldehyde

: 281211-15-2
[5(4'-iodophenyl)tetrakis-10,15,20-tris(3'',5''-di-tert-butylphenyl)porphyrinato]nickel(II)

Guidance literature:: Multi-step reaction with 2 steps

1.1: iodine / dichloromethane / 0.08 h / 40 °C / Microwave irradiation; Sealed tube

1.2: 0.25 h / Reflux

2.1: toluene / 1.5 h / Reflux

With iodine; In dichloromethane; toluene;
DOI:10.1021/acs.joc.8b02907