Chlorobis(pentafluoroethyl)phosphane

Base Information

• Chemical Name: Chlorobis(pentafluoroethyl)phosphane
• CAS No.: 35449-89-9
• Molecular Formula: C4Cl F10 P
• Molecular Weight: 304.45
• Hs Code.: 2903799090
• DSSTox Substance ID: DTXSID70373899
• Nikkaji Number: J2.946.629G
• Wikidata: Q82162286
• Mol file: 35449-89-9.mol

Synonyms:35449-89-9;chlorobis(pentafluoroethyl)phosphane;Chloro(bis-pentafluoroethyl)phosphine;Chloro-bis(1,1,2,2,2-pentafluoroethyl)phosphane;Bis(pentafluoroethyl)phosphinous chloride;(C2F5)2PCl;SCHEMBL1540867;chlorobis(perfluoroethyl)phosphine;DTXSID70373899;Chlorobis(pentafluoroethyl)phosphine;Chloro-bis-(pentafluoroethyl)phosphine;FT-0639260;bis(pentafluoroethyl)phosphinous acid chloride;A822815;chloro-bis(1,1,2,2,2-pentafluoroethyl)phosphine;chloranyl-bis[1,1,2,2,2-pentakis(fluoranyl)ethyl]phosphane

Chemical Property of Chlorobis(pentafluoroethyl)phosphane

Chemical Property:

• Boiling Point: 70.7°Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 4.93230
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 2
• Exact Mass: 303.9266463
• Heavy Atom Count: 16
• Complexity: 227

Purity/Quality:

98%min ^*data from raw suppliers

CHLORO(BIS-PENTAFLUOROETHYL)PHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,F
• Statements: 17-34
• Safety Statements: 17-26-36/37/39-43

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(F)(F)P(C(C(F)(F)F)(F)F)Cl)(F)(F)F

Technology Process of Chlorobis(pentafluoroethyl)phosphane

There total 8 articles about Chlorobis(pentafluoroethyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

bis(pentafluoroethyl)(diethylamino)phosphine (197703-79-0) → Chlor-bis-pentafluorethyl-phosphin (35449-89-9)

Guidance literature:

With hydrogenchloride; at -30 ℃; for 0.0833333h;

DOI:10.1002/ejic.201300364

Reference yield: 66.0%

tris(pentafluoroethyl)phosphane → Chlor-bis-pentafluorethyl-phosphin (35449-89-9)

Guidance literature:

tris(pentafluoroethyl)phosphane; With sodium hydroxide; In diethyl ether; water; for 0.5h;

With phenyltetrachlorophosphorane; In 1 ,6-dibromohexane; at 20 ℃; for 0.166667h;

DOI:10.1002/chem.201003048

Reference yield:

(C2F5)2POSnBu3 (1159100-60-3) → Chlor-bis-pentafluorethyl-phosphin (35449-89-9)

Guidance literature:

With phenyltetrachlorophosphorane;

DOI:10.1002/chem.201003048

upstream raw materials:

Bis(pentafluoraethyl)-jodphosphan

Pentafluoroethyl iodide

(C₂F₅)2POSnBu₃

sodium bis(pentafluoroethyl)phosphinite

Refernces

• 1、 Zakharov, Alexander V.,Vishnevskiy, Yury V.,Allefeld, Nadine,Bader, Julia,Kurscheid, Boris,Steinhauer, Simon,Hoge, Berthold,Neumann, Beate,Stammler, Hans-Georg,Berger, Raphael J. F.,Mitzel, Norbert W.. "Functionalized bis(pentafluoroethyl)phosphanes: Improved syntheses and molecular structures in the gas phase". . p. 3392 - 3404. Retrieved 2013/07/26.
• 2、 -. "Bis(perfluoralkyl)phosphinous acids and derivatives and use thereof". Page/Page column 18-19. . Retrieved 2011/06/19.