copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin

Base Information

• Chemical Name: copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin
• CAS No.: 84433-40-9
• Molecular Formula: C₄₅H₃₀CuN₆
• Molecular Weight: 718.319
• Mol file: 84433-40-9.mol

Synonyms:copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin

Chemical Property of copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin

Chemical Property:

Purity/Quality:

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Technology Process of copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin

There total 1 articles about copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

β-formyl-5,10,15,20-tetrakis(phenyl)porphyrin copper(II) (71763-49-0) → copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin (84433-40-9)

Guidance literature:

With hydrazine; In toluene; N2H4 was added to soln. of complex in toluene, soln. was refluxed for 15 h; Solvent was removed under vac., residue was chromd., recrystd. from CHCl3/heptane; elem. anal.;

Reference yield: 95.0%

copper(II) meso-tetraphenyl-2-(hydrazonomethyl)porphyrin (84433-40-9) + 3-isocyanato-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrole-1-oxyl (68212-42-0) → copper(II) meso-tetraphenyl-2-(2-((((2,2,5,5-tetramethyl-1-oxy-3-pyrrolinyl)amino)carbonyl)hydrazono)-methyl)porphyrin (84433-37-4)

Guidance literature:

In tetrahydrofuran; Isocyanate was added to a soln. of complex in dry THF, soln. was refluxed for 6 h; Solvent was removed under vac., product was recrystd. from CHCl3/heptane; elem. anal.;

upstream raw materials:

β-formyl-5,10,15,20-tetrakis(phenyl)porphyrin copper(II)

Downstream raw materials:

copper(II) meso-tetraphenyl-2-(2-((((2,2,5,5-tetramethyl-1-oxy-3-pyrrolinyl)amino)carbonyl)hydrazono)-methyl)porphyrin