(3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

Base Information

Chemical Name:(3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate
CAS No.:1383003-70-0
Molecular Formula:C₁₆H₁₉F₃O₄S
Molecular Weight:364.386
Hs Code.:

Synonyms:(3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

Suppliers and Price of (3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

Chemical Property:

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Technology Process of (3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

There total 4 articles about (3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: (3S,5R)-5-benzyl-3-ethyl-5-methyl-4-oxocyclopent-1-en-1-yl trifluoromethanesulfonate

: 1383003-70-0
(3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: With diisobutylaluminium hydride; In hexane; dichloromethane; Inert atmosphere;
DOI:10.1021/ja3032345

Reference yield:

: 856177-89-4
2-((benzyloxy)methyl)-2-methylcyclopentane-1,3-dione

: 1383003-70-0
(3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 4 steps

1: copper(ll) bromide / methanol / 1 h / Inert atmosphere; Reflux

2: C₃₈H₂₂F₁₂NO₂P; copper(II) bis(trifluoromethanesulfonate) / diethyl ether; hexane / 0.5 h / -78 - 20 °C / Inert atmosphere

3: diethyl ether; hexane / 20 °C / Inert atmosphere

4: diisobutylaluminium hydride / hexane; dichloromethane / Inert atmosphere

With C₃₈H₂₂F₁₂NO₂P; copper(II) bis(trifluoromethanesulfonate); diisobutylaluminium hydride; copper(ll) bromide; In methanol; diethyl ether; hexane; dichloromethane;
DOI:10.1021/ja3032345

Reference yield:

: 1383003-29-9
2-((benzyloxy)methyl)-2-methylcyclopent-4-ene-1,3-dione

: 1383003-70-0
(3S,4S,5S)-5-benzyl-3-ethyl-4-hydroxy-5-methylcyclopent-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 3 steps

1: C₃₈H₂₂F₁₂NO₂P; copper(II) bis(trifluoromethanesulfonate) / diethyl ether; hexane / 0.5 h / -78 - 20 °C / Inert atmosphere

2: diethyl ether; hexane / 20 °C / Inert atmosphere

3: diisobutylaluminium hydride / hexane; dichloromethane / Inert atmosphere

With C₃₈H₂₂F₁₂NO₂P; copper(II) bis(trifluoromethanesulfonate); diisobutylaluminium hydride; In diethyl ether; hexane; dichloromethane;
DOI:10.1021/ja3032345