cis-(CO)4Re(⁽¹³⁾CO)C₆H₅

Base Information

Chemical Name:cis-(CO)4Re(⁽¹³⁾CO)C₆H₅
CAS No.:83207-85-6
Molecular Formula:C₁₁H₅O₅Re
Molecular Weight:404.354
Hs Code.:

cis-(CO)4Re(<sup>(13)</sup>CO)C<sub>6</sub>H<sub>5</sub>

Synonyms:cis-(CO)4Re(⁽¹³⁾CO)C₆H₅

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of cis-(CO)4Re(⁽¹³⁾CO)C₆H₅

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Technology Process of cis-(CO)4Re(⁽¹³⁾CO)C₆H₅

There total 2 articles about cis-(CO)4Re(⁽¹³⁾CO)C₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 83214-26-0
(CO)5Re⁽¹³⁾COC₆H₅

: 83207-85-6
cis-(CO)4Re(⁽¹³⁾CO)C₆H₅

Guidance literature:: In acetone; A soln. of complex in acetone was heated at 96°C for 1.8 h in a sealed Fischer-Porter bottle;; evapd., ppt. was chromd. on silica gel, hexane;;
DOI:10.1021/ja00387a032

Reference yield: 49.0%

: 33634-75-2
sodium pentacarbonylrhenate

: 52947-05-4
[α-13C]benzoyl chloride

: 83207-85-6
cis-(CO)4Re(⁽¹³⁾CO)C₆H₅

: 83214-26-0
(CO)5Re⁽¹³⁾COC₆H₅

: phenylrheniumpentacarbonyl

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; C6H5(13)COCl was added to a THF soln. of complex;; sublimation at 85°C, 1E-3 mmHg, then at 25°C, 1E-3 mmHg; not sepd., detected by NMR spectra;;
DOI:10.1021/ja00387a032

Reference yield: 54.0%

: 83207-85-6
cis-(CO)4Re(⁽¹³⁾CO)C₆H₅

: 917-54-4
methyllithium

: 75-57-0
tetramethlyammonium chloride

: 83207-79-8
(CH₃)4N⁽¹⁺⁾*(CO)4Re(C₆H₅)(⁽¹³⁾COCH₃)^(1-)

: 83247-86-3
(CH₃)4N⁽¹⁺⁾*(CO)3(⁽¹³⁾CO)Re(C₆H₅)(COCH₃)^(1-)

: 83247-88-5
(CH₃)4N⁽¹⁺⁾*(CO)3(⁽¹³⁾CO)Re(C₆H₅)(COCH₃)^(1-)

: 83207-81-2
(CH₃)4N⁽¹⁺⁾*(CO)3(⁽¹³⁾CO)Re(C₆H₅)(COCH₃)^(1-)

: (CH₃)4N⁽¹⁺⁾*(CO)4Re(C₆H₅)(COCH₃)^(1-)

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; CH3Li was added to a soln. of complex in THF at -78°C, stirred at this temp. for 1 h, warmed to room temp., H2O was added, filtered, evapd., N(CH3)4Cl in CH2Cl2 was added;; CH2Cl2 layer was sepd., evapd., dissolved in THF, filtered, evapd., washed with ether and dried under vac.; labeled isomers were detected by NMR spectra;;
DOI:10.1021/ja00387a032