Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester

Base Information

• Chemical Name: Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester
• CAS No.: 101472-41-7
• Molecular Formula: C₂₉H₃₄O₃S
• Molecular Weight: 462.653

Synonyms:Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester

Chemical Property of Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester

There total 4 articles about Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

cis-1-(1-hydroxyethyl)-3-methyl<3.4>paracyclophane (101472-33-7) + p-toluenesulfonyl chloride (98-59-9) → Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaen-2-yl)-ethyl ester (101472-41-7)

Guidance literature:

With pyridine; at 0 - 25 ℃;

DOI:10.1021/jo00360a034

Reference yield:

1,4-bis(p-vinylphenyl)-butane (41996-99-0) → Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaen-2-yl)-ethyl ester (101472-41-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 25 percent / CF₃SO₃H / hexane / 0.33 h / 50 °C

3: 100 percent / diethyl ether

4: 100 percent / pyridine / 0 - 25 °C

With pyridine; trifluorormethanesulfonic acid; In diethyl ether; hexane;

DOI:10.1021/jo00360a034

Reference yield:

2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaene (101472-21-3) → Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaen-2-yl)-ethyl ester (101472-41-7)

Guidance literature:

Multi-step reaction with 3 steps

2: 100 percent / diethyl ether

3: 100 percent / pyridine / 0 - 25 °C

With pyridine; In diethyl ether;

DOI:10.1021/jo00360a034

upstream raw materials:

cis-1-(1-hydroxyethyl)-3-methyl<3.4>paracyclophane

p-toluenesulfonyl chloride

1,4-bis(p-vinylphenyl)-butane

2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaene

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 101472-41-7 Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester

Send

Send

Metric Ton KG G Pound L ML

Send

Send