Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3)

Base Information

• Chemical Name: Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3)
• CAS No.: 122395-74-8
• Molecular Formula: C₄₃H₃₇BrFeOP₂Pd
• Molecular Weight: 873.885
• Mol file: 122395-74-8.mol

Synonyms:Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3)

Chemical Property of Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3)

There total 1 articles about Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[1,1'-bis(diphenylphosphino)ferrocene]Pd(η(2)-cyclooctatetraene) (122395-71-5) + (E)-4-(2-bromo-vinyl)-anisole (6303-59-9,60592-52-1,27570-08-7) → Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3) (122395-74-8)

Guidance literature:

In tetrahydrofuran; Ar-atmosphere; 5 equivs. of olefin, -40°C; not isolated, determined by NMR spectroscopy;

DOI:10.1021/om00116a010

Reference yield:

Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-BrCH=CHC6H4OCH3) (122395-74-8) + [1,1'-bis(diphenylphosphino)ferrocene]Pd(η(2)-cyclooctatetraene) (122395-71-5) → (1,1`-bis(diphenylphosphino)ferrocene)Pd(p-OMeC6H4CHCH)Br

Guidance literature:

In tetrahydrofuran; Ar-atmosphere; -40°C; not isolated, determined by NMR spectroscopy;

DOI:10.1021/om00116a010

upstream raw materials:

[1,1'-bis(diphenylphosphino)ferrocene]Pd(η(2)-cyclooctatetraene)

(E)-4-(2-bromo-vinyl)-anisole