(R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid

Base Information

Chemical Name:(R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid
CAS No.:199286-35-6
Molecular Formula:C₁₆H₂₂O₂
Molecular Weight:246.349
Hs Code.:

Synonyms:(R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid

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Chemical Property of (R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid

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Technology Process of (R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid

There total 2 articles about (R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 199286-34-5
(R)-3-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-6-vinyl-tetrahydro-pyran-2-one

: 199286-35-6
(R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid

Guidance literature:: Multi-step reaction with 2 steps

1: Et₃N / CH₂Cl₂ / 0.5 h / -78 - 23 °C

2: 2.) aq. LiOH / 1.) toluene, reflux, 4.5 h, 2.) THF, 23 deg C, 15 min

With lithium hydroxide; triethylamine; In dichloromethane;
DOI:10.1021/ja973034o

Reference yield:

: tert-Butyl-dimethyl-{(R)-3-[2-(2-methyl-cyclohexa-1,4-dienyl)-ethyl]-6-vinyl-5,6-dihydro-4H-pyran-2-yloxy}-silane

: 199286-35-6
(R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid

Guidance literature:: With lithium hydroxide; Yield given. Multistep reaction; 1.) toluene, reflux, 4.5 h, 2.) THF, 23 deg C, 15 min;
DOI:10.1021/ja973034o

Reference yield: 79.0%

: 199286-35-6
(R)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-3-cyclohexenecarboxylic acid

: (1S,4S,5S)-1-[2-(2-methyl-1,4-cyclohexadienyl)ethyl]-4-iodo-6-oxa-7-oxobicyclo[3.2.1]octane

Guidance literature:: With iodine; sodium hydrogencarbonate; potassium iodide; In tetrahydrofuran; water; at 23 ℃; for 3h;
DOI:10.1021/ja973034o