5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin

Base Information

• Chemical Name: 5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin
• CAS No.: 85294-27-5
• Molecular Formula: C₆₇H₆₀N₈O₄
• Molecular Weight: 1041.26
• Mol file: 85294-27-5.mol

Synonyms:5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin

Chemical Property of 5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin

There total 7 articles about 5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-[3,5-Bis-(3-chlorocarbonyl-propyl)-phenyl]-butyryl chloride (85294-17-3) + (α,α,α,α,)-5--phenyl>-10,15,20-tris(o-aminophenyl)-21H,23H-porphine (85294-19-5) → 5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin (85294-27-5)

Guidance literature:

With pyridine; In dichloromethane; high dilution conditions;

DOI:10.1021/ja00348a018

Reference yield:

tetrakis-5,10,15,20-(o-aminophenyl)porphyrin (52199-35-6) → 5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin (85294-27-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 60 percent / pyridine / CH₂Cl₂ / 2 h

2: 85 percent / pyridine / CH₂Cl₂ / high dilution conditions

With pyridine; In dichloromethane;

DOI:10.1021/ja00348a018

Reference yield:

1,3,5-tris(2'-bromoethyl)benzene (18226-47-6) → 5,10,15-(1,3,5-tris(benzenetributyryl)tris(α,α,α-o-aminophenyl))-20-(α-o-pivalamidophenyl)porphyrin (85294-27-5)

Guidance literature:

Multi-step reaction with 4 steps

1: NaH / dimethylformamide / 14 h / Heating

2: 1.) NaH, 2.) aq. KOH, 3.) HCl

3: SOCl₂

4: 85 percent / pyridine / CH₂Cl₂ / high dilution conditions

With pyridine; hydrogenchloride; potassium hydroxide; thionyl chloride; sodium hydride; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/ja00348a018

upstream raw materials:

4-[3,5-Bis-(3-chlorocarbonyl-propyl)-phenyl]-butyryl chloride

(α,α,α,α,)-5--phenyl>-10,15,20-tris(o-aminophenyl)-21H,23H-porphine

tetrakis-5,10,15,20-(o-aminophenyl)porphyrin

1,3,5-tris(2'-bromoethyl)benzene