Technology Process of C39H50O7
There total 11 articles about C39H50O7 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrabutyl ammonium fluoride;
In
tetrahydrofuran;
at 20 ℃;
for 0.5h;
DOI:10.1021/ol102925d
- Guidance literature:
-
Multi-step reaction with 10 steps
1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 0 °C
1.2: 1 h / 50 °C
2.1: dimethylsulfide borane complex / tetrahydrofuran / 0 - 20 °C
2.2: 0 - 20 °C
3.1: diisobutylaluminium hydride / hexane; dichloromethane / 0 - 20 °C
3.2: 2.5 h
4.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C
5.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 19 h / 20 °C / Molecular sieve
6.1: zinc trifluoromethanesulfonate / tetrahydrofuran / 20 °C
7.1: sodium hydride / tetrahydrofuran; mineral oil / 2 h / 20 °C
7.2: 15 h
8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / -78 °C
9.1: n-heptane; dichloromethane / -78 - 0 °C
10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 20 °C
With
1H-imidazole; tetrapropylammonium perruthennate; dimethylsulfide borane complex; tetrabutyl ammonium fluoride; zinc trifluoromethanesulfonate; sodium hydride; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; 9-bora-bicyclo[3.3.1]nonane; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; hexane; n-heptane; dichloromethane; N,N-dimethyl-formamide; mineral oil;
1.2: Suzuki-Miyaura coupling;
DOI:10.1021/ol102925d
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: dimethylsulfide borane complex / tetrahydrofuran / 0 - 20 °C
1.2: 0 - 20 °C
2.1: diisobutylaluminium hydride / hexane; dichloromethane / 0 - 20 °C
2.2: 2.5 h
3.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C
4.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 19 h / 20 °C / Molecular sieve
5.1: zinc trifluoromethanesulfonate / tetrahydrofuran / 20 °C
6.1: sodium hydride / tetrahydrofuran; mineral oil / 2 h / 20 °C
6.2: 15 h
7.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / -78 °C
8.1: n-heptane; dichloromethane / -78 - 0 °C
9.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 20 °C
With
1H-imidazole; tetrapropylammonium perruthennate; dimethylsulfide borane complex; tetrabutyl ammonium fluoride; zinc trifluoromethanesulfonate; sodium hydride; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; hexane; n-heptane; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/ol102925d